5-((5-((2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinin-5-yl)thio)-4',5'-bis(methylthio)-[2,2'-bi(1,3-dithiolylidene)]-4-yl)thio)-2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinine | 1186011-39-1

• 英文名称: 5-((5-((2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinin-5-yl)thio)-4',5'-bis(methylthio)-[2,2'-bi(1,3-dithiolylidene)]-4-yl)thio)-2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinine
• CAS: 1186011-39-1
• 化学式: C₁₈H₁₈B₂F₄O₄S₈
• 分子量: 652.482
• InChiKey: HRADHXCAKXVAEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-[[2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-5-(2,4-dioxopentan-3-ylsulfanyl)-1,3-dithiol-4-yl]sulfanyl]pentane-2,4-dione 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以30%的产率得到5-((5-((2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinin-5-yl)thio)-4',5'-bis(methylthio)-[2,2'-bi(1,3-dithiolylidene)]-4-yl)thio)-2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinine
  参考文献：
  名称：

  Tetrathiafulvalenyl-acetylacetonate complexes of difluoroboron

  摘要：

  A series of tetrathiafulvalene (TTF) derivatives functionalized by one or two beta-diketonatoboron difluoride groups were synthesized through the addition of borontrifluoride to TTF Substituted by one or two acetylacetone functions. The influence of the beta-diketonatoboron difluoride moiety on the redox properties of the TTF has been investigated by cyclic voltammetry. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.05.041