5,6,7,8-tetrahydro-1-azaanthracene | 73922-33-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5,6,7,8-tetrahydro-1-azaanthracene
• 英文别名: 6,7,8,9-tetrahydrobenzoquinoline；Tetramethylen-chinolin；6,7,8,9-tetrahydro-benzo[g]quinoline；6,7,8,9-Tetrahydro-benzo[g]chinolin；6,7,8,9-Tetrahydrobenzo[g]quinoline
• CAS: 73922-33-5
• 化学式: C₁₃H₁₃N
• 分子量: 183.253
• InChiKey: GISFCMFDLARQDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5,6,7,8-tetrahydro-1-azaanthracene 生成 6,6',7,7',8,8',9,9'-Octahydro-2,2'-bi(benzochinolin
  参考文献：
  名称：

  HAGINIWA JOJU; HIGUCHI YOSHIHIRO; IKEDA SHIGEO, YAKUGAKU DZASSI, JAKUGAKU ZASSNI, J. PHARM. SOS. JAR., 1979, 99, NO 12, 1+

  摘要：

  DOI：
• 作为产物：
  描述：

  5,6,7,8-四氢-2-萘胺 在 盐酸 作用下， 反应 2.25h， 生成 5,6,7,8-tetrahydro-1-azaanthracene
  参考文献：
  名称：

  Takeuchi, Isao; Ushida, Makoto; Hamada, Yoshiki, Heterocycles, 1995, vol. 41, # 10, p. 2221 - 2232

  摘要：

  DOI：

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20190319198A1

  公开（公告）日：2019-10-17

  An organic light emitting device (OLED) that includes an anode, a cathode, and an organic layer disposed between the anode and the cathode. The organic layer includes a metal compound that comprises a ligand L A of Formula I, wherein the dashed lines represent coordination to a metal M. The metal M is selected from the groups consisting of Os, Ru, Ir, Rh, Pt, Pd, and Cu, and the metal is further coordinated to one or more ligand(s) L B , wherein the ligand(s) L B can be the same or different if more than one ligand L B is present. Optionally one or two of the ligand(s) L B can independently link to the ligand L A through one of R 1 to R 5 . The invention is also directed to a consumer product that includes an OLED, and the OLED includes an organic layer that includes a metal compound that comprises a ligand L A of Formula I.

  一种有机发光器件（OLED），包括阳极、阴极和位于阳极和阴极之间的有机层。有机层包括一个包含配体LA的化合物，其中虚线代表与金属M的配位。金属M选自Os、Ru、Ir、Rh、Pt、Pd和Cu组，金属进一步与一个或多个配体LB配位，如果有多个配体LB，则这些配体LB可以相同或不同。可选地，一个或两个配体LB可以独立地通过R1至R5中的一个连接到配体LA。该发明还涉及一种包括OLED的消费产品，该OLED包括一个包含配体LA的化合物的有机层。
• Albert et al., Journal of the Chemical Society, 1948, p. 1284,1290
  作者：Albert et al.

  DOI：——

  日期：——
• Inverse-electron-demanddiels-alder reactions of condensed pyridazines VI: Ring transformations of pyrido[2,3-d]pyridazine intog-fused quinolines
  作者：N. Haider、W. Staschek

  DOI：10.1007/bf00812249

  日期：1995.2

  A series of g-annelated quinolines was synthesized, employing pyrido[2,3-d]pyridazine as an azadiene in inverse-electron-demand Diels-Alder reactions with electron-rich dienophiles (enamines and a ketene-N,g-acetal). In cases where isomer mixtures were obtained, NOE difference spectroscopy was used for structural assignment.
• v. Braun; Gruber, Chemische Berichte, 1922, vol. 55, p. 1716
  作者：v. Braun、Gruber

  DOI：——

  日期：——