catena-poly[[(dipyrido[3,2-a:2',3'-c]phenazine-κ2N,N')nickel(II)]-μ-2,6-dipicolinato-κ4O2,NO6:O2'] | 1111192-60-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: catena-poly[[(dipyrido[3,2-a:2',3'-c]phenazine-κ2N,N')nickel(II)]-μ-2,6-dipicolinato-κ4O2,NO6:O2']
• CAS: 1111192-60-9
• 化学式: C₂₅H₁₃N₅NiO₄
• 分子量: 506.099
• InChiKey: XSJDHACWTLLLNZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二吡啶并[3,2-a:2',3'-c]吩嗪 、 吡啶-2,6-二甲酸 、 nickel(II) nitrate hexahydrate 在 NaOH 作用下， 以 水 为溶剂， 生成 catena-poly[[(dipyrido[3,2-a:2',3'-c]phenazine-κ2N,N')nickel(II)]-μ-2,6-dipicolinato-κ4O2,NO6:O2']
  参考文献：
  名称：

  A one-dimensional nickel(II) coordination polymer containing 2,6-dipicolinate and dipyrido[3,2-a:2′,3′-c]phenazine

  摘要：

  A new coordination polymer, catena-poly[[(dipyrido[3,2-a:2',3'-c]phenazine-kappa N-2,N') nickel(II)]-mu-2,6-dipicolinato-kappa O-4(2),N,O-6:O-2'], [Ni(C7H3NO4)(C18H10N4)](n), exhibits a one-dimensional structure in which 2,6-dipicolinate acts as a bridging ligand interconnecting adjacent nickel(II) centers to form a chain structure. The asymmetric unit contains one Ni-II center, one dipyrido[3,2-a:2',3'-c] phenazine ligand and one 2,6-dipicolinate ligand. Each Ni II center is six-coordinated and surrounded by three N atoms and three O atoms from one dipyrido[3,2-a:2',3'-c] phenazine ligand and two different 2,6-dipicolinate ligands, leading to a distorted octahedral geometry. Adjacent chains are linked by pi-pi stacking interactions and weak interactions to form a three-dimensional supramolecular network.

  DOI：

  10.1107/s0108270107053851