methyl O-(2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl)-(1-2)-O-<2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl-(1-3)>-4,6-di-O-methyl-β-D-glucopyranoside | 76790-45-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: methyl O-(2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl)-(1-2)-O-<2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl-(1-3)>-4,6-di-O-methyl-β-D-glucopyranoside
• CAS: 76790-45-9
• 化学式: C₂₉H₅₄O₁₆
• 分子量: 658.738
• InChiKey: ILXYPIVOXVWVDF-XIYTZBAFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.38
• 重原子数：
  45.0
• 可旋转键数：
  18.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  147.68
• 氢给体数：
  0.0
• 氢受体数：
  16.0

反应信息

• 作为反应物：
  描述：

  methyl O-(2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl)-(1-2)-O-<2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl-(1-3)>-4,6-di-O-methyl-β-D-glucopyranoside 生成 1,5-O-di-acetyl-2,3,4,6-tetra-O-methyl-D-glucitol 、 1,2,3,5-tetra-O-acetyl-4,6-di-O-methylglucitol
  参考文献：
  名称：

  Silver trifluoromethanesulfonate-promoted Koenigs-Knorr reaction of Methyl 4,6-O-benzylidene-β-d-glucopyranoside with 2,3,4,6-tetra-O-acetyl-α-d-glucopyranosyl bromide

  摘要：

  DOI：

  10.1016/s0008-6215(00)85199-x
• 作为产物：
  描述：

  methyl 2,3-di-O-β-D-galactopyranosyl-α-D-glucopyranoside 、 碘甲烷 在 sodium hydride 作用下， 生成 methyl O-(2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl)-(1-2)-O-<2,3,4,6-tetra-O-methyl-β-D-glucopyranosyl-(1-3)>-4,6-di-O-methyl-β-D-glucopyranoside
  参考文献：
  名称：

  Silver trifluoromethanesulfonate-promoted Koenigs-Knorr reaction of Methyl 4,6-O-benzylidene-β-d-glucopyranoside with 2,3,4,6-tetra-O-acetyl-α-d-glucopyranosyl bromide

  摘要：

  DOI：

  10.1016/s0008-6215(00)85199-x