5-benzoyl-1-(3-methoxy-2-hydroxyphenylmethylmethyleneamino)-4-phenyl-1H-pyrimidine-2-one | 835878-05-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-benzoyl-1-(3-methoxy-2-hydroxyphenylmethylmethyleneamino)-4-phenyl-1H-pyrimidine-2-one
• CAS: 835878-05-2
• 化学式: C₂₅H₁₉N₃O₄
• 分子量: 425.444
• InChiKey: DWPYCAYCHPERHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.74
• 重原子数：
  32.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  93.78
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  5-benzoyl-1-(3-methoxy-2-hydroxyphenylmethylmethyleneamino)-4-phenyl-1H-pyrimidine-2-one 、 zinc(II) acetate dihydrate 以 甲醇 、 氯仿 为溶剂， 以65%的产率得到5-benzoyl-1-(3-methoxy-2-hydroxyphenylmethylmethyleneamino)-4-phenyl-1H-pyrimidine-2-one zinc(II) complex*2H2O
  参考文献：
  名称：

  Synthesis, Characterization, and Thermal Investigation of Some Metal Complexes Containing Polydentate ONO-Donor Heterocyclic Schiff Base Ligand

  摘要：

  Cu(II), Co(II), Ni(H), and Zn(II) metal complexes with new heterocyclic Schiff base derived from 1-amino-5-benzoyl-4-phenyl-IH-pyrimidine-2-one and 3-methoxysalicylaidehyde have been synthesized and characterized on the basis of elemental analyses, electronic IR, and H-1 NMR spectra, and also by aid of molar conductivity measurements, maenetic moment measurements, and thermogravinietric analyses. It has been found that the Schiff base behaves as a neutral bidentate (NO) and tridentate (ONO) ligand forming chelates with 1 : 2 (metal : ligand) stoichiometry. Octahedral configuration is suggested for metal complexes. The conductivity data for the Ni(II) complexes are consistent with those expected for a 1 : 2 electrolyte.

  DOI：

  10.1023/b:ruco.0000040726.57728.a3