aluminium tri-isoamyl | 25016-92-6

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: aluminium tri-isoamyl
• 英文别名: aluminium triisopentylate；Aluminium-triisopentylat；Aluminium-tris-(3-methyl-butylat)；triisopentyloxy aluminum；Aluminiumisoamylat
• CAS: 25016-92-6
• 化学式: C₁₅H₃₃AlO₃
• 分子量: 288.407
• InChiKey: VMBBGSGAVWGRCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.01
• 重原子数：
  7.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.06
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  aluminium tri-isoamyl 、 异戊醛 生成 异戊酸异戊酯
  参考文献：
  名称：

  Tischtschenko, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1906, vol. 38, p. 499

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸异戊酯 、 aluminum tri-sec-butoxide 以 neat (no solvent) 为溶剂， 以90%的产率得到aluminium tri-isoamyl
  参考文献：
  名称：

  Buining, Paul A.; Pathmamanaharan, Chellappah; Jansen, J. Ben H., Journal of the American Ceramic Society, 1991, vol. 74, p. 1303 - 1307

  摘要：

  DOI：
• 作为试剂：
  描述：

  乙醛 、 三氯乙醛 在 aluminium tri-isoamyl 作用下， 生成 三氯乙酸乙酯
  参考文献：
  名称：

  Nakai, Biochemische Zeitschrift, 1924, vol. 152, p. 267

  摘要：

  DOI：

文献信息

• 一种脱除烷氧基铝中铁杂质的方法
  申请人：中国石油化工股份有限公司

  公开号：CN110407668B

  公开（公告）日：2021-12-17

  一种脱除烷氧基铝中铁杂质的方法，包括在烷氧基铝的醇溶液中加入支持电解质，混合均匀形成电解液，在电解液中插入铝电极为阴极，惰性电极为阳极，于烷氧基铝醇溶液沸点±80℃的温度下进行电解反应，反应后得到高纯烷氧基铝醇溶液。该法使用电解法脱除烷氧基铝中的铁杂质，操作简单、效果好。
• Über die Verwendung von Aluminium-Alkoholaten zu Umesterungs- und Verseifungsreaktionen
  作者：Karl W. Rosenmund、Felix Zymalkowski、Eckart Güssow

  DOI：10.1002/ardp.19532860704

  日期：——
• Vorlaender, Chemische Berichte, 1897, vol. 30, p. 2262
  作者：Vorlaender

  DOI：——

  日期：——
• Mid-term Results of the Ross Procedure
  作者：Domenico Paparella、Tirone E. David、Susan Armstrong、Joan Ivanov

  DOI：10.1111/j.1540-8191.2001.tb00533.x

  日期：2001.7

  Although the Ross procedure has been performed for over three decades, its role in the management of patients with aortic valve disease is not well established. This study reviews our experience with this operation. From 1990 to 1999, 155 patients underwent the Ross procedure. The mean age of 106 men and 49 women was 35 years. Most patients (85%) had congenital aortic valve disease. The pulmonary autograft was implanted in the subcoronary position in 2 patients, as an aortic root inclusion in 78, and aortic root replacement in 75. The follow-up extended from 9 to 114 months, mean of 45 +/- 28 months, and it was complete. All patients have had Doppler echocardiographic studies. There was only one operative and one late death. The survival was 98% at 7 years. The freedom from 3+ or 4+ aortic insufficiency was 86% at 7 years and the freedom from reoperation on the pulmonary autograft was 95% at 7 years. Dilation of the aortic annulus and/or sinotubular junction was the most common cause of aortic insufficiency. One patient required three reoperations on the biological pulmonary valve. Most patients (96%) have no cardiac symptoms. The Ross procedure has provided excellent functional results in most patients, but progressive aortic insufficiency due to dilation of the aortic annulus and/or sinotubular junction is a potential problem in a number of patients.
• Nef, Justus Liebigs Annalen der Chemie, 1895, vol. 287, p. 342 Anm.
  作者：Nef

  DOI：——

  日期：——