Ionic Complexes of Xe and C2H2Produced by the Radiolysis of These Gases
摘要:
Binary mixtures of acetylene and the noble gases were irradiated by 90 ev electrons at pressures up to 1.3 mm in the ionization chamber of a research mass spectrometer. Various proportions of the mixtures and a range of pressures were employed in this study. Ionic complexes, [XeC2H]+ and [XeC2H2]+, were observed in the C2H2–Xe system. The intensity ratio [XeC2H2]+/[XeC2H]+ increased linearly with increasing pressure. No ionic complexes were observed in the other mixtures. A series of reactions involving Xe+ is presented.