{Hg(S-2,4,6-i-Pr3C6H2)2} | 124511-91-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {Hg(S-2,4,6-i-Pr3C6H2)2}
• CAS: 124511-91-7
• 化学式: 2C₁₅H₂₃S*Hg
• 分子量: 671.417
• InChiKey: RATTZFTZWXYEIE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.96
• 重原子数：
  17.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  2,4,6-Triisopropylthiophenol 、 mercury dichloride 在 (C₂H₅)3N 作用下， 以 甲醇 为溶剂， 以92%的产率得到{Hg(S-2,4,6-i-Pr3C6H2)2}
  参考文献：
  名称：

  Block, Eric; Brito, Maria; Gernon, Michael, Inorganic Chemistry, 1990, vol. 29, # 17, p. 3172 - 3181

  摘要：

  DOI：

文献信息

• Santos, Rodolfo A.; Gruff, Eric S.; Koch, Stephen A., Journal of the American Chemical Society, 1991, vol. 113, # 2, p. 469 - 475
  作者：Santos, Rodolfo A.、Gruff, Eric S.、Koch, Stephen A.、Harbison, Gerard S.

  DOI：——

  日期：——
• Sterically hindered thiolato, selenolato and tellurolato complexes of mercury(II)
  作者：Manfred Bochmann、Kevin J. Webb

  DOI：10.1039/dt9910002325

  日期：——

  Mercury(II) complexes of sterically demanding arenechalcogenolato ligands, Hg(EC6H2R3-2,4,6)2 (E = S or Se; R = Me, Pr(i) or Bu(t): E = Te; R = Me or Pr(i)) have been prepared. Whereas complexes carrying smaller aryl substituents (R = Me) are polymeric, those with R = Pr(i) and Bu(t) form linear two-co-ordinate molecules. For a given R, the volatility of the complexes increases for E = S < Se < Te, while the thermal stability decreases in the same sequence. The preferred thermal decomposition pathway is reductive elimination to metallic mercury and the corresponding diaryl dichalcogenide. The oxidative addition of diaryl ditellurides to mercury and the reverse reaction are dependent on solvent polarity and steric factors; in the case of Te this leads to an unexpected decrease in stability with increased steric hindrance of the aryl substituents, R = Me > Pr(i) >> Bu(t).
• Trigonal-planar [M(SR)3]1- complexes of cadmium and mercury. Structural similarities between mercury-cysteine and cadmium-cysteine coordination centers
  作者：Eric S. Gruff、Stephen A. Koch

  DOI：10.1021/ja00159a054

  日期：1990.1