Trichloronitridomolybdaen(VI)-tetrahydrofuran | 143480-72-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Trichloronitridomolybdaen(VI)-tetrahydrofuran
• CAS: 143480-72-2
• 化学式: C₄H₈O*Cl₃MoN
• 分子量: 288.413
• InChiKey: HBZZGNNUKHASOD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.88
• 重原子数：
  10.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  33.02
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  Trichloronitridomolybdaen(VI)-tetrahydrofuran 在 LiO-t-Bu 作用下， 以 not given 为溶剂， 生成 nitridomolybdenum(VI) tris(tert-butoxide)
  参考文献：
  名称：

  Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen

  摘要：

  Methylation of the nitridomolybdenum(VI) complex N = Mo(O-t-C4H9)3 (2), obtained from N = MoCl3.THF (1), is achieved by use of dimethylzinc, resulting in the formation of the novel tetranuclear products [N = Mo(CH3)2(O-t-C4H9).1/2py]4 (3) (py = 4-t-butylpyridine). A single-crystal X-ray diffraction study reveals four N = Mo(CH3)2 units being connected through the nitrogen atoms, thereby forming unsymmetrical, linear Mo = N-Mo units. The cubane-type zinc complex [CH3ZnO-t-C4H9]4 (4; X-ray diffraction study) is also formed.

  DOI：

  10.1016/0022-328x(92)86013-t
• 作为产物：
  描述：

  钼,二(乙酰腈)四氯- 在 NaN₃ 、 THF 作用下， 以 乙腈 为溶剂， 以93%的产率得到Trichloronitridomolybdaen(VI)-tetrahydrofuran
  参考文献：
  名称：

  Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen

  摘要：

  Methylation of the nitridomolybdenum(VI) complex N = Mo(O-t-C4H9)3 (2), obtained from N = MoCl3.THF (1), is achieved by use of dimethylzinc, resulting in the formation of the novel tetranuclear products [N = Mo(CH3)2(O-t-C4H9).1/2py]4 (3) (py = 4-t-butylpyridine). A single-crystal X-ray diffraction study reveals four N = Mo(CH3)2 units being connected through the nitrogen atoms, thereby forming unsymmetrical, linear Mo = N-Mo units. The cubane-type zinc complex [CH3ZnO-t-C4H9]4 (4; X-ray diffraction study) is also formed.

  DOI：

  10.1016/0022-328x(92)86013-t

文献信息

• Hydrolysis and reductive hydrolysis of nitridomolybdenum(VI) complexes: a model reaction in the purported catalytic cycles of dinitrogen fixation
  作者：Norikazu Ueyama、Hiroko Fukase、Hiroakizaima、Seiichi Kishida、Akira Nakamura

  DOI：10.1016/0304-5102(87)87001-3

  日期：1987.12