8-propoxy-octa-1,6t-diene | 51586-86-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 8-propoxy-octa-1,6t-diene
• 英文别名: 1-n-Propoxyoctadien (2-t,7)；(6E)-8-propoxyocta-1,6-diene
• CAS: 51586-86-8
• 化学式: C₁₁H₂₀O
• 分子量: 168.279
• InChiKey: PWUSWSFBPPFEDI-CMDGGOBGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  丙醇 、 1,3-丁二烯 在 Pd catalyst 作用下， 生成 8-propoxy-octa-1,6t-diene
  参考文献：
  名称：

  Beger,J.; Reichel,H., Journal fur praktische Chemie (Leipzig 1954), 1973, vol. 315, p. 1067 - 1076

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING ETHERS
  申请人：KURARAY CO., LTD.

  公开号：EP1760061A1

  公开（公告）日：2007-03-07

  A method for producing ethers comprises the following steps: initiating telomerization process of a conjugated diene compound with an hydroxyl compound represented by the following formula (I):         R1OH     (I) in the presence of a palladium compound, a tertiary isocyanide represented by the following formula (II):         R2NC     (II) , and a base; and adding halfway through the telomerization process a tertiary phosphine represented by the following formula (III):         PR3R4R5     (III) (the respective symbols are defined in the description).

  一种生产醚的方法包括以下步骤： 启动共轭二烯化合物与下式 (I) 所代表的羟基化合物的端聚过程： R1OH (I) 在钯化合物存在下，加入下式 (II) 所代表的叔异氰酸酯： R2NC (II) 和一种碱；以及 在端粒化过程的中途加入下式（III）代表的叔膦： PR3R4R5 (III) (各符号在说明中定义）。
• BISPHOSPHITE AND PROCESS FOR PRODUCING ALDEHYDE COMPOUND WITH THE BISPHOSPHITE
  申请人：Kuraray Co., Ltd., Kurashiki Plant

  公开号：EP1728796B1

  公开（公告）日：2010-03-17
• METHOD FOR PRODUCING ALDEHYDE USING BISPHOSPHITE AND GROUP 8-10 METAL COMPOUND, AND SUCH BISPHOSPHITE
  申请人：Kuraray Co., Ltd.

  公开号：EP2003138B1

  公开（公告）日：2013-10-09
• Bisphosphite and process for producing aldehyde compound with the bisphosphite
  申请人：Tsuji Tomoaki

  公开号：US20070197834A1

  公开（公告）日：2007-08-23

  Bisphosphite(s) represented by the following general formula (I): wherein Ar 1 and Ar 2 are each independently a substituted or unsubstituted arylene group; R 1 , R 2 , R 7 and R 8 are each independently a substituted or an unsubstituted alkyl group, a substituted or an unsubstituted aryl group or a substituted or an unsubstituted heterocyclic group, or R 1 and R 2 or R 7 and R 8 may together form a ring with their associated oxygen atoms and phosphor atom; and R 3 , R 4 , R 5 and R 6 are each independently a hydrogen atom or an alkyl group, with the proviso that the carbon atom bearing R 3 and R 4 and the carbon atom bearing R 5 and R 6 are bound to the respective arylene groups at the ortho position to the Ar 1 —Ar 2 bond. Also provided is a process for producing aldehyde(s) using the bisphosphite and a Group 8 to 10 metal compound. A composition comprising the bisphosphite and a Group 8 to 10 metal compound is further provided.
• Method For Producing Ethers
  申请人：Tokuyasu Jin

  公开号：US20080262272A1

  公开（公告）日：2008-10-23

  A method for producing ethers comprises the following steps: initiating telomerization process of a conjugated diene compound with an hydroxyl compound represented by the following formula (I): R 1 OH   (I) in the presence of a palladium compound, a tertiary isocyanide represented by the following formula (II): R 2 NC   (II) , and a base; and adding halfway through the telomerization process a tertiary phosphine represented by the following formula (III): PR 3 R 4 R 5 (III) (the respective symbols are defined in the description).