Dy(4-[(N-furfural)amino]antypirine)3(NCS)3 | 354565-36-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Dy(4-[(N-furfural)amino]antypirine)3(NCS)3
• 英文别名: dysprosium(3+);4-(furan-2-ylmethylideneamino)-1,5-dimethyl-2-phenylpyrazol-3-one;triisothiocyanate
• CAS: 354565-36-9
• 化学式: C₅₁H₄₅DyN₁₂O₆S₃
• 分子量: 1180.69
• InChiKey: GTMHFRMFMCTNEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.46
• 重原子数：
  73
• 可旋转键数：
  9
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  246
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  Dy(4-[(N-furfural)amino]antypirine)3(NCS)3 以 neat (no solvent) 为溶剂， 生成 dysprosium((III) oxide
  参考文献：
  名称：

  THE SYNTHESIS, STRUCTURE, AND BONDING IN SOME LANTHANIDE(III) COORDINATION COMPOUNDS OF 4-[(N-FURFURAL)AMINO]ANTIPYRINE

  摘要：

  Some seven-, eight-, nine- and ten-coordinated complexes of lanthanide(III) with 4-[(N-furfural)amino]antipyrine (FFAP) were prepared in ethanol or methanol as solvent. The complexes have the general composition LnX(3).nFFAP (Ln = La, Pr, Nd, Sm, Gd? Tb or Dy; X = NO3- n = 2; X = NCS-, n = 2 or 3; X = ClO4-, n = 4). The structure and bonding of these compounds of high coordination number were established with the help of chemical analyses, conductance, molecular weights, magnetic measurements, IR and electronic spectral data. The thermal stabilities of these compounds were also studied by TGA.

  DOI：

  10.1081/sim-100002046
• 作为产物：
  描述：

  N,N'-bis(2-hydroxy-3-methoxybenzylidene)-1,2-phenylenediamine 、 dysprosium(III) thiocyanate 以 乙醇 为溶剂， 以72%的产率得到Dy(4-[(N-furfural)amino]antypirine)3(NCS)3
  参考文献：
  名称：

  THE SYNTHESIS, STRUCTURE, AND BONDING IN SOME LANTHANIDE(III) COORDINATION COMPOUNDS OF 4-[(N-FURFURAL)AMINO]ANTIPYRINE

  摘要：

  Some seven-, eight-, nine- and ten-coordinated complexes of lanthanide(III) with 4-[(N-furfural)amino]antipyrine (FFAP) were prepared in ethanol or methanol as solvent. The complexes have the general composition LnX(3).nFFAP (Ln = La, Pr, Nd, Sm, Gd? Tb or Dy; X = NO3- n = 2; X = NCS-, n = 2 or 3; X = ClO4-, n = 4). The structure and bonding of these compounds of high coordination number were established with the help of chemical analyses, conductance, molecular weights, magnetic measurements, IR and electronic spectral data. The thermal stabilities of these compounds were also studied by TGA.

  DOI：

  10.1081/sim-100002046