1,4,5-triphenyl-1H-imidazol-2-amine | 1360998-10-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,4,5-triphenyl-1H-imidazol-2-amine
• 英文别名: 1,4,5-Triphenylimidazol-2-amine
• CAS: 1360998-10-2
• 化学式: C₂₁H₁₇N₃
• 分子量: 311.386
• InChiKey: ZZSISLASAKIPRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.8
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4,5-triphenyl-1H-imidazol-2-amine 在 盐酸 作用下， 以 甲醇 、 水 为溶剂， 生成 1,4,5-triphenyl-1H-imidazol-2-amine hydrochloride
  参考文献：
  名称：

  A modular approach to the synthesis of 1,4,5-substituted-2-aminoimidazoles

  摘要：

  Diversified 1,4,5-substituted-2-aminoimidazoles were rapidly assembled via sequential N-H insertion and Grignard addition to alpha-diazoesters. Lead compounds were identified as antibiotics against Gram-positive bacteria with an MIC value as low as 2 mu g/mL. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.12.090
• 作为产物：
  描述：

  N-methoxy-N-methyl-2-phenyl-2-(phenylamino)acetamide 在 sodium hydroxide 作用下， 以 四氢呋喃 、 乙醇 、 水 为溶剂， 反应 5.0h， 生成 1,4,5-triphenyl-1H-imidazol-2-amine
  参考文献：
  名称：

  A modular approach to the synthesis of 1,4,5-substituted-2-aminoimidazoles

  摘要：

  Diversified 1,4,5-substituted-2-aminoimidazoles were rapidly assembled via sequential N-H insertion and Grignard addition to alpha-diazoesters. Lead compounds were identified as antibiotics against Gram-positive bacteria with an MIC value as low as 2 mu g/mL. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.12.090

文献信息

• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ORGANIQUES ÉLECTROLUMINESCENTS ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT ASSOCIÉ
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2011136484A1

  公开（公告）日：2011-11-03

  Provided are novel organic electroluminescent compounds and an organic electroluminescent device using the same. Since the organic electroluminescent compound exhibits high luminous efficiency in blue color and excellent life property, it may be used to manufacture OLEDs having very superior operation life.

  提供了新颖的有机电致发光化合物以及使用这些化合物的有机电致发光装置。由于这种有机电致发光化合物在蓝色方面表现出高发光效率和优秀的寿命特性，因此可以用于制造具有非常优越运行寿命的OLED。
• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] COMPOSÉS ORGANIQUES ÉLECTROLUMINESCENTS INNOVANTS ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT LES UTILISANT
  申请人：DOW ADVANCED DISPLAY MATERIALS

  公开号：WO2010107244A2

  公开（公告）日：2010-09-23

  Disclosed are a novel organic electroluminescent compound and an organic electroluminescent device comprising the same. When used as host material of organic electroluminescent material of an OLED device, the disclosed organic electroluminescent compound exhibits high luminous efficiency and excellent life property of the material as compared to conventional host material. Therefore, it can be used to manufacture OLEDs having very good operation life.