(4S,E)-4,5,5,5-tetrafluoro-4-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)pent-2-en-1-ol | 1345976-77-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (4S,E)-4,5,5,5-tetrafluoro-4-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)pent-2-en-1-ol
• CAS: 1345976-77-3
• 化学式: C₁₁H₅F₁₇O₃
• 分子量: 508.132
• InChiKey: CPFQXKODNSZGGA-OWOJBTEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.41
• 重原子数：
  31.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  38.69
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  1-iodo-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecyl acetate 在 potassium hydroxide 作用下， 以 正己烷 为溶剂， 反应 3.0h， 以15%的产率得到1,2-Epoxy-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecane
  参考文献：
  名称：

  A study of the physico-chemical features of the [(perfluoroalkyl)methyl]oxirane amino derivatives based on the hexafluoropropylene oxide trimer

  摘要：

  The 1,2-epoxy-4,6,6,7,9,9,10,10,11,11,11-undecafluoro-4,7-bis(trifluoromethyl)-5,8-dioxaundecane was synthesized for the first time on the basis of the hexafluoropropylene oxide trimer. We showed that it reacted with diethylamine, morpholine, or N-methylpiperazine to afford the product of regioselective cleavage of the oxirane ring. The processing of nano-sized copper powder with a solution of the obtained hydroxyamine solution in acetone allowed the formation of the hydrophobic metal coating.

  DOI：

  10.1134/s1070363211090155