methoxydimethylgermane-t | 1243627-27-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: methoxydimethylgermane-t
• CAS: 1243627-27-1
• 化学式: C₃H₁₀GeO
• 分子量: 136.694
• InChiKey: MHUIFJOCQKXCCI-IBTRZKOZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.62
• 重原子数：
  5.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  甲基叔丁基醚 、 Me2GeT(1+) 以 gas 为溶剂， 以74%的产率得到methoxydimethylgermane-t
  参考文献：
  名称：

  A radiochemical study of isomerization of dimethylgermylium ion, with the reaction of Me2HGe+ cation with methyl tert-butyl ether as example

  摘要：

  The reaction of dimethylgermylium ion with methyl tert-butyl ether in the gas phase was studied by the radiochemical method, and the mechanisms of the corresponding ion-molecule reactions were suggested. The possibility of the existence of germylium ions generated by the nuclear-chemical method was proved by the example of dimethylgermylium ion. Possible pathways of transformation of (CH3)(2)HGe+ cation into other isomeric forms were analyzed by B3LYP calculations with 6-31G* and aug-cc-pVDZ basis sets.

  DOI：

  10.1134/s1066362210010224