2,6-di-tert-butyl-4-(1-benzoyl-3-phenylpropyl)phenol | 474379-75-4

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 2,6-di-tert-butyl-4-(1-benzoyl-3-phenylpropyl)phenol
• 英文别名: 2-(3,5-Ditert-butyl-4-hydroxyphenyl)-1,4-diphenylbutan-1-one
• CAS: 474379-75-4
• 化学式: C₃₀H₃₆O₂
• 分子量: 428.615
• InChiKey: RGZZIYFJWBKRMY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• High boiling inhibitors for distillable, polymerizable monomers
  申请人：CROMPTON CORPORATION, a corporation of the State of Delaware

  公开号：US20030065177A1

  公开（公告）日：2003-04-03

  Disclosed herein are compounds of the structure 1 wherein R 1 , R 2 , and R 3 are organic radicals of C 1 to C 20 , such that the combination of the three contain at least twelve carbon atoms and R 3 is bound to the methylene carbon atom between X and the aromatic ring by at least one saturated carbon atom, allowing it to be easily separated from the polymerizable monomer by distillation; R 1 and R 2 have sufficient steric bulk to protect the phenol from reacting with an alkoxy group or halogen bound to silicon; and X is a neutral heteroatomic radical of oxygen, nitrogen, or phosphorus; and their use as inhibitors for the polymerization of (meth)acryloxysilanes.

  本文公开了结构1的化合物，其中R1、R2和R3是C1到C20的有机基团，三者的组合至少包含十二个碳原子，并且R3通过至少一个饱和碳原子与X和芳香环之间的亚甲基碳原子结合，从而可以通过蒸馏轻松地与聚合单体分离；R1和R2具有足够的立体阻碍作用，以保护苯酚不与硅键结合的烷氧基或卤素反应；X是氧、氮或磷的中性杂原子基团；以及它们作为(meth)acryloxilanes聚合抑制剂的应用。
• HIGH BOILING INHIBITORS FOR DISTILLABLE, POLYMERIZABLE MONOMERS
  申请人：Crompton Corporation

  公开号：EP1417209A1

  公开（公告）日：2004-05-12
• US6475347B1
  申请人：——

  公开号：US6475347B1

  公开（公告）日：2002-11-05
• [EN] HIGH BOILING INHIBITORS FOR DISTILLABLE, POLYMERIZABLE MONOMERS<br/>[FR] INHIBITEURS A POINT D'EBULLITION ELEVE POUR MONOMERES DISTILLABLES ET POLYMERISABLES
  申请人：CROMPTON CORP

  公开号：WO2003014130A1

  公开（公告）日：2003-02-20

  Disclosed herein are compounds of structure (I), wherein R1, R2, and R3 are organic radicals of C1 to C20, such that the combination of the three contain at least twelve carbon atoms and R3 is bound to the methylene carbon atom between X and the aromatic ring by at least one saturated carbon atom, allowing it to be easily separated from the polymerizable monomer by distillation; R1 and R2 having sufficient steric bulk to protect the phenol from reacting with an alkoxy group or halogen bound to silicon; and X is a neutral heteroatomic radical of oxygen, nitrogen, or phosphorous; and their use as inhibitors for the polymerization of (meth)acryloxysilanes.