diphenyl[N,N'-bis(1-phenyl-3-methyl-4-benzoyl-5-pyrazolone)-1,3-propylenediiminato]tin(IV) | 251324-70-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: diphenyl[N,N'-bis(1-phenyl-3-methyl-4-benzoyl-5-pyrazolone)-1,3-propylenediiminato]tin(IV)
• CAS: 251324-70-6
• 化学式: C₄₉H₄₂N₆O₂Sn
• 分子量: 865.621
• InChiKey: OBMDUTUGPYNIAZ-GMALXUCKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1-phenyl-3-methyl-4-benzoyl-5-pyrazolone)2-1,3-propylenediamine Schiff base 、 二苯基二氯化锡 在 Et₃N 作用下， 以 苯 为溶剂， 以71.26%的产率得到diphenyl[N,N'-bis(1-phenyl-3-methyl-4-benzoyl-5-pyrazolone)-1,3-propylenediiminato]tin(IV)
  参考文献：
  名称：

  Synthesis and characterization of diorganotin(IV) complexes of tetradentate Schiff bases: crystal structure of n-Bu2Sn(Vanophen)

  摘要：

  Diorganotin(IV) complexes of the general formula R2SnL (R=Ph, n-Bu and Me) have been prepared from diorganotin(IV) dichlorides (R2SnCl2) acid tetradentate Schiff bases (H2L) containing N2O2 donor atoms in the presence of triethylamine in benzene. The Schiff bases, H2L, were derived from salicylaldehyde, 3-methoxysalicylaldehyde (o-vanillin), 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone and diamines such as o-phenylenediamine and 1,3-propylenediamine. The complexes were characterized by IR, NMR (H-1, C-13, Sn-119) and elemental analysis. The structure of the complex, n-Bu2Sn(Vanophen), was determined using single crystal X-ray diffraction, The tin atom has a distorted octahedral coordination, with the Vanophen ligand occupying the four equatorial positions and the n-butyl groups in the trans axial positions, Six-coordinated distorted octahedral structures have been proposed for all diorganotin(IV) complexes studied here, as they possess similar spectroscopic data. (C) 1994 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00171-0