(S)-(3-hydroxy-3,5-dimethylhex-1-yn-1-yl)gold | 221682-14-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (S)-(3-hydroxy-3,5-dimethylhex-1-yn-1-yl)gold
• CAS: 221682-14-0
• 化学式: C₈H₁₃AuO
• 分子量: 322.157
• InChiKey: XDAFDNMYXYRQLU-DDWIOCJRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.29
• 重原子数：
  10.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  (S)-(3-hydroxy-3,5-dimethylhex-1-yn-1-yl)gold 、 三苯基膦 以 甲苯 为溶剂， 以92%的产率得到(S)-(3-hydroxy-3,5-dimethylhex-1-yn-1-yl)(triphenyl-l5-phosphaneyl)gold
  参考文献：
  名称：

  Use of phosphine gold acetylides [(R3P)AuCCR] to form phosphine gold derivatives of tetra-iron and penta-iron clusters

  摘要：

  Five new gold acetylides, [AuC equivalent to CR], with hydroxyl or amino functions in the organic radical R have been prepared. From these, nine phosphine complexes [(R3P)AuC equivalent to CR] with R = Ph or Cy were synthesised. Reactions between the phosphine gold acetylides [(Ph3P)AuC equivalent to CC(Me)(OH)Et] or [(Cy3P)AuC equivalent to CC(Me)(OH)Et] and the iron carbonyl cluster [Et4N][Fe4N(CO)(12)] gave both neutral [(R3P)AuFe4N(CO)(12)] and ionic compounds [(R3P)(2)Au][Fe4N(CO)(12)]. Reaction with the penta-iron cluster [Et4N][Fe5N(CO)(14)] afforded [(R3P)(2)Au][Fe5N(CO)(14)], [(R3P)(2)Au][Fe4N(CO)(12)] and [(R3P)AuFe4N(CO)(12)]. The gold-iron clusters were characterised with spectroscopic methods (IR, NMR and Mossbauer) and in the case Of [(Cy3P)AuFe4N(CO)(12)] a single-crystal X-ray analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.045
• 作为产物：
  描述：

  chloroauric acid 、 3,5-二甲基-1-己炔-3-醇 在 KBr 、 SO₂ 作用下， 以 水 、 丙酮 为溶剂， 生成 (S)-(3-hydroxy-3,5-dimethylhex-1-yn-1-yl)gold
  参考文献：
  名称：

  Use of phosphine gold acetylides [(R3P)AuCCR] to form phosphine gold derivatives of tetra-iron and penta-iron clusters

  摘要：

  Five new gold acetylides, [AuC equivalent to CR], with hydroxyl or amino functions in the organic radical R have been prepared. From these, nine phosphine complexes [(R3P)AuC equivalent to CR] with R = Ph or Cy were synthesised. Reactions between the phosphine gold acetylides [(Ph3P)AuC equivalent to CC(Me)(OH)Et] or [(Cy3P)AuC equivalent to CC(Me)(OH)Et] and the iron carbonyl cluster [Et4N][Fe4N(CO)(12)] gave both neutral [(R3P)AuFe4N(CO)(12)] and ionic compounds [(R3P)(2)Au][Fe4N(CO)(12)]. Reaction with the penta-iron cluster [Et4N][Fe5N(CO)(14)] afforded [(R3P)(2)Au][Fe5N(CO)(14)], [(R3P)(2)Au][Fe4N(CO)(12)] and [(R3P)AuFe4N(CO)(12)]. The gold-iron clusters were characterised with spectroscopic methods (IR, NMR and Mossbauer) and in the case Of [(Cy3P)AuFe4N(CO)(12)] a single-crystal X-ray analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.045