exo-N-(p-hydroxyphenyl)-3,6-epoxy-4-cyclohexene-1,2-dicarboximide | 209005-76-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: exo-N-(p-hydroxyphenyl)-3,6-epoxy-4-cyclohexene-1,2-dicarboximide
• 英文别名: (3aR,4S,7R,7aS)-2-(4-hydroxyphenyl)-3a,4,7,7a-tetrahydro-4,7-epoxyisoindole-1,3-dione
• CAS: 209005-76-5
• 化学式: C₁₄H₁₁NO₄
• 分子量: 257.246
• InChiKey: PFJLLNMPZGGZHX-BKUVIOGVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  66.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  exo-N-(p-hydroxyphenyl)-3,6-epoxy-4-cyclohexene-1,2-dicarboximide 在 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939
• 作为产物：
  描述：

  exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride 、 对氨基苯酚 在 溶剂黄146 作用下， 反应 0.17h， 以68%的产率得到exo-N-(p-hydroxyphenyl)-3,6-epoxy-4-cyclohexene-1,2-dicarboximide
  参考文献：
  名称：

  通过开环易位聚合反应制备的新型光致变色吲哚并苯并螺并吡喃型均聚物的合成和光谱性质

  摘要：

  通过紧张的双环吲哚并苯并螺并吡喃衍生物的开环易位聚合反应，制备了三种新型的基于光致变色的吲哚并苯并螺并吡喃衍生物的均聚物。均聚物可溶于常见的有机溶剂，并通过凝胶渗透色谱分析确定显示出异常高的多分散性。溶液中的紫外可见吸收光谱分析表明，保留了各个单体具有吸引力的光致变色行为。

  DOI：

  10.1016/j.dyepig.2009.12.002

文献信息

• The synthesis and spectroscopic properties of novel, photochromic indolinobenzospiropyran-based homopolymers prepared via ring-opening metathesis polymerization
  作者：Sam-Rok Keum、Su-Mi Ahn、Se-Jung Roh、So-Young Ma

  DOI：10.1016/j.dyepig.2009.12.002

  日期：2010.6

  Three types of novel photochromic indolinobenzospiropyran-based homopolymers were prepared via the ring-opening metathesis polymerization of the strained bicyclic indolinobenzospiropyran derivative. The homopolymers were soluble in common organic solvents and displayed unusually high polydispersity as determined by gel permeation chromatographic analysis. UV–visible absorption spectroscopy analysis

  通过紧张的双环吲哚并苯并螺并吡喃衍生物的开环易位聚合反应，制备了三种新型的基于光致变色的吲哚并苯并螺并吡喃衍生物的均聚物。均聚物可溶于常见的有机溶剂，并通过凝胶渗透色谱分析确定显示出异常高的多分散性。溶液中的紫外可见吸收光谱分析表明，保留了各个单体具有吸引力的光致变色行为。
• Synthesis of novel pyrazole-linked norcantharidin derivatives of substituted aromatic amines with efficient 1,3-dipolar cycloaddition
  作者：Liping Deng、Weifeng Tao、Jianguo Lv、Wei Wang

  DOI：10.1002/jhet.119

  日期：2009.7

  Highly efficient, practical and convenient synthesis of twelve compounds by the [3+2] 1, 3-dipolar cycloaddition reaction of norcantharidin derivatives of substituted aromatic amines with two hydrazines in the presence of chloramine-T. J. Heterocyclic Chem., (2009).

  高效，实用，方便地合成的十二种化合物通过[3 + 2] 1，3-偶极环取代取代的芳香胺的降冰伞烷素衍生物与两个肼的存在下的三偶极环加成反应氯胺-T。J.杂环化​​学，（2009）。
• Synthesis of Pyrazole-linked Norcantharidin Analogues of Substituted Chromones
  作者：Wei Wang、Liping Deng、Shenlong Tang、Qing Qian

  DOI：10.1002/jhet.1665

  日期：2016.9

  Eighteen novel pyrazole‐linked norcantharidin derivatives substituted by chromone ring were synthesized in a single step by the [3+2] 1,3‐dipolar cycloaddition reaction of norcantharidin derivatives of substituted aromatic amines with hydrazone in the presence of chloramine‐T as compared to the conventional method.

  在存在氯胺-T的情况下，通过取代芳香胺的降鸟th啶衍生物与with的[3 + 2] 1,3-偶极环加成反应，可以一步合成十八个被色酮环取代的吡唑连接的降鸟烷配体衍生物。常规方法。
• Novel Synthesis of Photochromic Polymers via ROMP
  作者：Andrew J. Myles、Zengrong Zhang、Guojun Liu、Neil R. Branda

  DOI：10.1021/ol006040p

  日期：2000.9.1

  Ring-opening metathesis polymerization (ROMP) of a photochromic 1,2-bis(3-thienyl)cyclopentene monomer generated a series of novel polymers. All polymers exhibit reversible light-activated interconversion between their colorless-open and their colored-closed forms.
• Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes
  作者：Andrew J. Myles、Neil R. Branda

  DOI：10.1021/ma0211939

  日期：2003.1.1

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.