4-[2-(5-Chloro-2-methyl-thiophen-3-yl)-cyclopent-1-enyl]-5-methyl-thiophene-2-carboxylic acid 4-((1S,2R,6S,7R)-3,5-dioxo-10-oxa-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-phenyl ester | 300664-84-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 4-[2-(5-Chloro-2-methyl-thiophen-3-yl)-cyclopent-1-enyl]-5-methyl-thiophene-2-carboxylic acid 4-((1S,2R,6S,7R)-3,5-dioxo-10-oxa-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-phenyl ester
• 英文别名: [4-[(3aS,4R,7S,7aR)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-(5-chloro-2-methylthiophen-3-yl)cyclopenten-1-yl]-5-methylthiophene-2-carboxylate
• CAS: 300664-84-0
• 化学式: C₃₀H₂₄ClNO₅S₂
• 分子量: 578.109
• InChiKey: ACJNFVBLJHRKMF-XOMBCNSKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  39
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  129
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4-[2-(5-Chloro-2-methyl-thiophen-3-yl)-cyclopent-1-enyl]-5-methyl-thiophene-2-carboxylic acid 4-((1S,2R,6S,7R)-3,5-dioxo-10-oxa-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-phenyl ester 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939
• 作为产物：
  描述：

  exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride 在 三乙胺 作用下， 以 溶剂黄146 为溶剂， 反应 0.17h， 生成 4-[2-(5-Chloro-2-methyl-thiophen-3-yl)-cyclopent-1-enyl]-5-methyl-thiophene-2-carboxylic acid 4-((1S,2R,6S,7R)-3,5-dioxo-10-oxa-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-4-yl)-phenyl ester
  参考文献：
  名称：

  Novel Synthesis of Photochromic Polymers via ROMP

  摘要：

  Ring-opening metathesis polymerization (ROMP) of a photochromic 1,2-bis(3-thienyl)cyclopentene monomer generated a series of novel polymers. All polymers exhibit reversible light-activated interconversion between their colorless-open and their colored-closed forms.

  DOI：

  10.1021/ol006040p

文献信息

• Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes
  作者：Andrew J. Myles、Neil R. Branda

  DOI：10.1021/ma0211939

  日期：2003.1.1

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.
• Novel Synthesis of Photochromic Polymers via ROMP
  作者：Andrew J. Myles、Zengrong Zhang、Guojun Liu、Neil R. Branda

  DOI：10.1021/ol006040p

  日期：2000.9.1

  Ring-opening metathesis polymerization (ROMP) of a photochromic 1,2-bis(3-thienyl)cyclopentene monomer generated a series of novel polymers. All polymers exhibit reversible light-activated interconversion between their colorless-open and their colored-closed forms.