2,3,6,7-tetramethoxy-9,10-di(4-pyridyl)-9,10-dihydroanthracen | 1392277-15-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,3,6,7-tetramethoxy-9,10-di(4-pyridyl)-9,10-dihydroanthracen
• 英文别名: 4-(2,3,6,7-Tetramethoxy-10-pyridin-4-yl-9,10-dihydroanthracen-9-yl)pyridine
• CAS: 1392277-15-4
• 化学式: C₂₈H₂₆N₂O₄
• 分子量: 454.525
• InChiKey: VHOPLMOXKDNDAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  62.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-吡啶甲醛 、 邻苯二甲醚 在 硫酸 作用下， 以 二氯甲烷 、 水 为溶剂， 以41.8%的产率得到2,3,6,7-tetramethoxy-9,10-di(4-pyridyl)-9,10-dihydroanthracen
  参考文献：
  名称：

  Water-inducing molecular self-assembly of amphiphilic molecules into nanofibers

  摘要：

  We present investigations on the microcosmic self-assembly process of new synthesized amphiphilic TPDP molecules. It can be seen that pure TPDP nanofibers with smooth surfaces can be obtained by reprecipitation method using ethanol as good solvent and water as poor solvent. In the self-assembly process, during the water adding to the amphiphilic molecules' saturated solution, the amphiphilic molecules firstly assembled into needle-like small rods. With an increase in the self-assembled time, a large number of the nanofibers are produced. The assembly behavior was revealed in the course of direct in situ monitoring of its growth with optical microscopy. Field emission scanning electron microscopy was adopted to characterize the morphologies of the products. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2011.08.029