methyl-(diphenoxyphosphoryl) carbamate | 95295-87-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methyl-(diphenoxyphosphoryl) carbamate
• 英文别名: diphenoxyphosphoryl-carbamic acid methyl ester；Diphenoxyphosphoryl-carbamidsaeure-methylester；N-Diphenylphosphono-carbamidsaeure-methylester
• CAS: 95295-87-7
• 化学式: C₁₄H₁₄NO₅P
• 分子量: 307.243
• InChiKey: LKDXCLVAIJDDID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.61
• 重原子数：
  21.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  73.86
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  methyl-(diphenoxyphosphoryl) carbamate 生成 diphenoxyphosphoryl-carbamic acid butyl ester; sodium-compound
  参考文献：
  名称：

  Kirsanow; Shmurowa, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 1002,1005; engl. Ausg. S. 1084, 1086

  摘要：

  DOI：
• 作为产物：
  描述：

  (Chlor-diphenoxy-phosphazo)-kohlensaeure-methylester 在 乙醇 作用下， 生成 methyl-(diphenoxyphosphoryl) carbamate
  参考文献：
  名称：

  Derkach,G.I. et al., Journal of general chemistry of the USSR, 1963, vol. 33, p. 551 - 555

  摘要：

  DOI：

文献信息

• Kirsanow; Shmurowa, Zhurnal Obshchei Khimii, 1956, vol. 26, p. 2642,2643, 2645; engl. Ausg. S. 2947, 2949
  作者：Kirsanow、Shmurowa

  DOI：——

  日期：——
• Spectroscopy and Kinetics of Triplet (Diphenoxyphosphoryl)nitrene
  作者：Michael Houser、Shane Kelley、Vincent Maloney、Matthew Marlow、Kathy Steininger、Hao Zhou

  DOI：10.1021/j100020a016

  日期：1995.5

  Triplet (diphenoxyphosphoryl)nitrene (3) was studied by solution phase laser flash photolysis, low-temperature absorption spectroscopy, and low-temperature EPR spectroscopy. In ethanol, an absorption maximum at 345 nm was observed upon laser flash photolysis of diphenyl phosphorazidate (1) and assigned to the triplet nitrene (r = 3.8 +/- 0.6 mu s). After irradiation of 1 in an EPA glass at 77 K, an absorption attributed to the triplet nitrene was observed at 336 am. The zero field splitting parameters from the EPR spectrum of the nitrene in EPA glass at 77 K were \D/hc\ = 1.5408 cm(-1) and \E/hc\ = 0.007 39 cm(-1). Stronger transient absorptions observed in hydroxylic solvents support the proposal that hydrogen bonding catalyzes intersystem crossing in nitrenes. [(a) Schuster, G. B.; Platz, M. S. In Advances in Photochemistry; Volman, D., Hammond, G., Neckers, D., Eds.; John Wiley and Sons: New York, 1992; Vol. 17. (b) Poe, R.; Grayzar, J.; Young, M. J. T.; Leyva, E.; Schnapp, K. A.; Platz, M. S. J. Am. Chem. Sec. 1991, 113, 3209. (c) Schnapp, K. A.; Platz, M. S. Bioconjugate Chem. 1993, 4, 178.]