10-undecyloxymethyl-3,6,9,12-tetraoxatricosan-1-ol | 201995-29-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 10-undecyloxymethyl-3,6,9,12-tetraoxatricosan-1-ol
• 英文别名: 2-[2-[2-[1,3-di(undecoxy)propan-2-yloxy]ethoxy]ethoxy]ethanol
• CAS: 201995-29-1
• 化学式: C₃₁H₆₄O₆
• 分子量: 532.846
• InChiKey: ZJDRASYYDVCUAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.49
• 重原子数：
  37.0
• 可旋转键数：
  33.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.38
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  10-undecyloxymethyl-3,6,9,12-tetraoxatricosan-1-ol 在 sodium 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成 10-undecyloxymethyl-3,6,9,12-tetraoxatricosyl 2-acetamido-2-deoxy-β-L-glucopyranoside
  参考文献：
  名称：

  Syntheses of l-glucosamine donors for 1,2-trans-glycosylation reactions

  摘要：

  Two new L-glucosarnine donors, that is pent-4-enyl 3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-beta-L-glucopyranoside 16 and ethyl 3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-l-thio-beta-L-glucopyranoside 21 were prepared in 12 steps from L-arabinose. The reaction pathway uses 3,4,6-tri-O-acetyl-L-glucal 5, and then 3,4,6-tri-O-acetyl-2-deoxy-2-iodO-alpha-L-mannopyranosyl azide 8 as intermediates. The latter, together with donors 16 and 21, were used for preparing L-glucosamine neoglycolipids. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2006.12.011
• 作为产物：
  描述：

  1-chloro-10-undecyloxymethyl-3,6,9,12-tetraoxatricosane 在 sodium hydroxide 、 四丁基溴化铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 22.5h， 生成 10-undecyloxymethyl-3,6,9,12-tetraoxatricosan-1-ol
  参考文献：
  名称：

  Synthesis and interfacial behavior of three homologous glycero neoglycolipids with various chain lengths

  摘要：

  Three neoglycolipids la-e derived from glycerol were synthezised and their molecular arrangements were studied at the air/water interface through Langmuir-Blodgett technique. The common structural features of these neoglycolipids are: a triethyleneglycol spacer at C-2 of glycerol, a GlcNAc hydrophilic head group at the end of the spacer, two saturated aliphatic chains at C-l and C-3 of glycerol, linked by ether bonds. Compounds la-e differ only by the length of their lipid moieties. By increasing the hydrocarbon chain length from C-11 to C-16, a densely packed state was reached in the monolayer. The compression isotherms displayed an expanded state during the whole compression for compounds la and Ic bearing two C-11 or one C-11 and one C-16 chains. Compound 1b bearing two C-16 chains displayed a quite different interfacial behavior. The transfer of these monolayers onto a solid substrate can be obtained only with a trigger molecule, a phosphatidic acid. (C) 1997 Elsevier Science Ireland Ltd.

  DOI：

  10.1016/s0009-3084(97)00076-5