4-(chlorostanniomethyl)-1-phenylquinolinium chloride | 415726-05-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 4-(chlorostanniomethyl)-1-phenylquinolinium chloride
• 英文别名: chloro-[(1-phenylquinolin-1-ium-4-yl)methyl]tin;chloride
• CAS: 415726-05-5
• 化学式: C₁₆H₁₃ClNSn*Cl
• 分子量: 408.902
• InChiKey: SKWZVEOEBJVNJC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.48
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  tin(ll) chloride 、 1-phenyl-4-(trifluoroacetoxycadmiomethyl)quinolinium trifluoroacetate 以 乙醇 为溶剂， 以35%的产率得到4-(chlorostanniomethyl)-1-phenylquinolinium chloride
  参考文献：
  名称：

  摘要：

  Consecutive treatment of methyl-substituted quinolinium and 2,6-diarylpyrilium perchlorates with sodium ethylate and equimolar amount of anhydrous cadmium(II) trifluoroacetate gives 2- and 4-methylenecadmium-containing salts of the above heterocyclic cations in 80-97% yields. The reactions of the cadmium-containing quinolinium and pyrilium salts with hydrochloric acid, acetic anhydride, mercuric trifluoroacetate, SnCl2, and nickel(II) trifluoroacetate, resulting in substitution of the CdOCOCF3 group by hydrogen, Ac, HgOCOCF3, SnCl, and NiOCOCF3, respectively, were studied.

  DOI：

  10.1023/a:1013109905880