(p-anisylsalicylaldiminato)(8-hydroxyquinolinato)cobalt(II) hydrate | 560101-37-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: (p-anisylsalicylaldiminato)(8-hydroxyquinolinato)cobalt(II) hydrate
• CAS: 560101-37-3
• 化学式: C₂₃H₁₈CoN₂O₃*H₂O
• 分子量: 447.416
• InChiKey: JUJNEVIIQQRECS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  8-羟基喹啉 、 2-((4-甲氧基苯亚氨基)甲基)苯酚 、 cobalt(II) acetate 以 甲醇 为溶剂， 生成 (p-anisylsalicylaldiminato)(8-hydroxyquinolinato)cobalt(II) hydrate
  参考文献：
  名称：

  摘要：

  Several new mixed ligand complexes of Ni(II) and Co(II) of p-tolylsalicylaldimine (Sal-TH) or p-anisylsalicylaldimine (Sal-AH) with 8-hydroxyquinoline (HOx), benzohydroxamic acid (BH2) or alpha-picoline (alpha-pic) have been synthesized. The complexes have the general formulae: [M(Sal-T)L], [M(Sal-A)L].H2O or [Ni(Sal-T)(2)(alpha-pic)(2)].H2O where M=Ni(II) or Co(II), Sal-T=p-tolylsalicylaldiminate, Sal-A=p-anisylsalicylaldiminate, L=8-hydroxyquinolinate or benzohydroxamate and alpha-pic=alpha-picoline. Analytical, conductivity and spectral data support a square planar structure for Co( II) complexes and octahedral structure for Ni( II) complexes. The thermal behaviour of the complexes has been studied by TG and DTG techniques. It was proposed that the decomposition of the complexed Schiff base takes place via a radical mechanism while for 8-hydroxyquinolinate or benzohydroxamate via proton transfer. Kinetic parameters of the thermal decomposition process have been computed by means of Coats-Redfern and Horowitz-Metzger methods.

  DOI：

  10.1023/a:1016190522455