| 1365566-02-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1365566-02-4
• 化学式: C₆₄H₈O₂
• 分子量: 808.766
• InChiKey: INEPTTOYZOOBMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.03
• 重原子数：
  66.0
• 可旋转键数：
  0.0
• 环数：
  33.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  1,3-丁二醇 、 足球烯 在 碘苯二乙酸 、 [双(三氟乙酰氧基)碘]苯 、 iron(II) chloride 作用下， 以 氯苯 为溶剂， 反应 1.0h， 以38%的产率得到
  参考文献：
  名称：

  Facile Access to Novel [60]Fullerenyl Diethers and [60]Fullerene–Sugar Conjugates via Annulation of Diol Moieties

  摘要：

  A general and facile annulation of various diol motifs to [60]fullerene has been developed. This protocol can afford not only 6- to 10-membered-ring fullerenyl diethers in one step from simple acyclic diols but also directly couple [60]fullerene with a variety of structurally diverse sugars. The [60]fullerene-sugar conjugates formed do not require any linker moiety and maintain their inherent structural integrity. The electrochemistry of the fullerenyl diethers and [60]fullerene-sugar conjugates has also been investigated.

  DOI：

  10.1021/acs.orglett.5b00536

文献信息

• TsOH-mediated reaction of aziridinofullerene with diols for the preparation of fullerene-fused dioxygenated ring compounds
  作者：Jun Wu、Fa-Bao Li、Xiao-Feng Zhang、Ji-Long Shi、Li Liu

  DOI：10.1039/c5ra03751d

  日期：——

  Reaction of aziridinofullerene with diols promoted by p-toluenesulfonic acid affords various fullerene-fused dioxygenated ring compounds with six- to ten-membered heterocycles.

  将aziridinofullerene与二醇在p-甲苯磺酸的促进下反应，得到各种带有六至十个成员杂环的富勒烯融合二氧化环化合物。
• Fullerenyl Boronic Esters: Ferric Perchlorate-Mediated Synthesis and Functionalization
  作者：Fa-Bao Li、Xun You、Tong-Xin Liu、Guan-Wu Wang

  DOI：10.1021/ol300398n

  日期：2012.4.6

  Fullerenyl boronic esters have been prepared by a ferric perchlorate-promoted reaction of [60]fullerene with various arylboronic acids. The obtained fullerenyl boronic esters could undergo further functionalization with diols to afford C-60-fused dioxane/dioxepane derivatives. A possible reaction mechanism for the formation of fullerenyl boronic esters has been proposed.