[Cu(2-carboxyphenylhydrazoethylcyanoacetate(-1H))(methanol)2(H2O)][NO3]*CH3OH | 841233-15-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Cu(2-carboxyphenylhydrazoethylcyanoacetate(-1H))(methanol)2(H2O)][NO3]*CH3OH
• CAS: 841233-15-6
• 化学式: CH₄O*C₁₄H₂₀CuN₃O₇*NO₃
• 分子量: 499.922
• InChiKey: YZWVDHCMCRAWOP-ROSNILEWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(2-carboxyphenylhydrazoethylcyanoacetate(-1H))(methanol)2(H2O)][NO3]*CH3OH 以 neat (no solvent) 为溶剂， 生成 [Cu(2-carboxyphenylhydrazoethylcyanoacetate(-1H))(methanol)2(H2O)][NO3]
  参考文献：
  名称：

  Synthesis and Characterization of New Transition and Actinide Metal Complexes of a Hydrazone Ligand. Mixed‐Ligand Complexes, Pyrolysis Products, and Biological Activity

  摘要：

  The chelating properties the hydrazone ligand 2-carboxyphenythydrazoethylcyanoacetate (H2L) have been studied. A new series of binary mononuclear complexes were prepared from the reaction of the hydrazone ligand (H2L) with the metal ions, Cd(H), Cu(II), Ni(H), Co(II), Th(IV), and UO2(VI), in the presence of LiOH as a deprotonating agent. The binary Cu(II) complex of H2L was reacted with the ligands 1,10-Phenanthroline or 2-aminopyridine to form mixed-ligand complexes. The binary complexes of Cu(11) and Ni(II) are suggested to have octahedral configurations. The Cd(II) and Co(II) complexes are suggested to have tetrahedral and/or square-planar geometries, respectively. The Th(IV) and UO2(VI) complexes are suggested to have octahedral and dodecahedral geometries, respectively. The mixed-ligand complexes have octahedral configurations. Also, new complexes were obtained pyrolytically as the previous complexes decompose through several isolable as well as non-isolable intermediates during heating. The structures of all complexes and the corresponding thermal products were elucidated by elemental analyses, conductance, IR and electronic absorption spectra, magnetic moments, H-1 NMR and TG-DSC measurements, as well as by mass spectroscopy. The ligand and some of the metal complexes were found to activate the enzyme pectinlyase.

  DOI：

  10.1081/sim-200026202
• 作为产物：
  描述：

  甲醇 、 copper(II) nitrate trihydrate 、 2-carboxyphenylhydrazoethylcyanoacetate 在 LiOH*H₂O 作用下， 以 甲醇 、 水 为溶剂， 以79%的产率得到[Cu(2-carboxyphenylhydrazoethylcyanoacetate(-1H))(methanol)2(H2O)][NO3]*CH3OH
  参考文献：
  名称：

  Synthesis and Characterization of New Transition and Actinide Metal Complexes of a Hydrazone Ligand. Mixed‐Ligand Complexes, Pyrolysis Products, and Biological Activity

  摘要：

  The chelating properties the hydrazone ligand 2-carboxyphenythydrazoethylcyanoacetate (H2L) have been studied. A new series of binary mononuclear complexes were prepared from the reaction of the hydrazone ligand (H2L) with the metal ions, Cd(H), Cu(II), Ni(H), Co(II), Th(IV), and UO2(VI), in the presence of LiOH as a deprotonating agent. The binary Cu(II) complex of H2L was reacted with the ligands 1,10-Phenanthroline or 2-aminopyridine to form mixed-ligand complexes. The binary complexes of Cu(11) and Ni(II) are suggested to have octahedral configurations. The Cd(II) and Co(II) complexes are suggested to have tetrahedral and/or square-planar geometries, respectively. The Th(IV) and UO2(VI) complexes are suggested to have octahedral and dodecahedral geometries, respectively. The mixed-ligand complexes have octahedral configurations. Also, new complexes were obtained pyrolytically as the previous complexes decompose through several isolable as well as non-isolable intermediates during heating. The structures of all complexes and the corresponding thermal products were elucidated by elemental analyses, conductance, IR and electronic absorption spectra, magnetic moments, H-1 NMR and TG-DSC measurements, as well as by mass spectroscopy. The ligand and some of the metal complexes were found to activate the enzyme pectinlyase.

  DOI：

  10.1081/sim-200026202