1-[2-(2-tert-butoxy-1-methyl-ethoxy)-1-methyl-ethoxy]-propan-2-ol | 58797-59-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-[2-(2-tert-butoxy-1-methyl-ethoxy)-1-methyl-ethoxy]-propan-2-ol
• 英文别名: 1-[1-[1-[(2-Methylpropan-2-yl)oxy]propan-2-yloxy]propan-2-yloxy]propan-2-ol
• CAS: 58797-59-4
• 化学式: C₁₃H₂₈O₄
• 分子量: 248.363
• InChiKey: SPBMDONZLSUYOD-UHFFFAOYSA-N

物化性质

• 沸点：
  312.8±22.0 °C(Predicted)
• 密度：
  0.951±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  47.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  potassium tert-butylate 、 methyloxirane 以 甲苯 、 叔丁醇 为溶剂， 生成 1-[2-(2-tert-butoxy-1-methyl-ethoxy)-1-methyl-ethoxy]-propan-2-ol
  参考文献：
  名称：

  Chlebicki,J., Roczniki Chemii, 1974, vol. 48, p. 1241 - 1253

  摘要：

  DOI：

文献信息

• Fabric care composition and method for using same
  申请人：Sivik Robert Mark

  公开号：US20050003981A1

  公开（公告）日：2005-01-06

  Compositions for treating fabric articles comprising novel detersive surfactants that provide improved cleaning performance (e.g, removal of laundry soils) in dry cleaning applications. Method for using the compositions in a dry cleaning application is also provided.

  本发明涉及用于处理织物物品的组合物，包括新型洗涤表面活性剂，可在干洗应用中提供改进的清洁性能（例如，去除洗涤污垢）。本发明还提供了在干洗应用中使用该组合物的方法。
• LITHOGRAPHIC PRINTING PLATE PRECURSOR AND LITHOGRAPHIC PRINTING PROCESS
  申请人：OOHASHI Hidekazu

  公开号：US20110054212A1

  公开（公告）日：2011-03-03

  A lithographic printing plate precursor, which comprises: a support; an image-recording layer; and a protective layer, in this order, wherein at least one of the image-recording layer and the protective layer comprises a phosphonium salt having a specific structure, and a lithographic printing process, which comprises: exposing a lithographic printing plate precursor; supplying an oil-based ink and a fountain solution comprising a phosphonium salt having a specific structure to the exposed lithographic printing plate precursor on a printing machine to remove an unexposed area of an image-recording layer; and conducting printing.

  一种光刻印刷版前体，包括：支撑体；图像记录层；以及保护层，依次排列，其中图像记录层和保护层中至少有一层包含具有特定结构的磷酸铵盐；以及一种光刻印刷工艺，包括：曝光光刻印刷版前体；在印刷机上向曝光的光刻印刷版前体提供具有特定结构的磷酸铵盐的油墨和喷泉溶液，以去除图像记录层中未曝光区域；进行印刷。
• Novel polyvinyl alcohol and process for producing polyvinyl alcohol by hydrolysis catalysed by acids
  申请人：Kuraray Co., Ltd.

  公开号：EP0328102A2

  公开（公告）日：1989-08-16

  The polyvinyl alcohol of the present invention is a partially saponified polyvinyl alcohol having a saponification degree of 70 to 98 mol% and containing a larger amount of methanol-soluble substances than that contained in polyvinyl alcohols having the same saponification degree obtained by known processes, and is novel. The process for producing polyvinyl alcohol of the present invention comprises saponifying polyvinyl esters in a solvent of a polyoxyalkylene ether having in the molecule thereof a structural unit represented by the general formula [I]: wherein R' and R2 each represents an alkylene group having 2 to 5 carbon atoms in the main chain thereof, which may be substituted with a lower alkyl group or lower alkoxy group; t is an integer of 0 or 1; m and n each represents 0 or an integer of 1 to 10; and I + m + n > 2; with the catalyst of an organic (aliphatic or aromatic) sulfonic acid at an elevated temperature in the presence of water. The process can produce polyvinyl alcohol having a higher saponification degree at a higher reaction rate than conventional hydrolysis processes catalysed by acids.

  本发明的聚乙烯醇是一种部分皂化的聚乙烯醇，其皂化度为 70 至 98 摩尔%，与通过已知工艺获得的具有相同皂化度的聚乙烯醇相比，含有更多的甲醇可溶物，具有新颖性。 本发明生产聚乙烯醇的工艺包括在聚氧亚烷基醚的溶剂中对聚乙烯醇酯进行皂化，聚氧亚烷基醚的分子中含有通式[I]所代表的结构单元： 其中 R' 和 R2 分别代表在其主链上具有 2 至 5 个碳原子的亚烷基，该亚烷基可被低级烷基或低级烷氧基取代；t 为 0 或 1 的整数；m 和 n 分别代表 0 或 1 至 10 的整数；且 I + m + n > 2； 有机（脂肪族或芳香族）磺酸催化剂，在有水存在的高温下进行。与传统的以酸为催化剂的水解工艺相比，该工艺能以更高的反应速率生产出皂化度更高的聚乙烯醇。
• CATALYST FOR RING-OPENING POLYMERIZATION OF ALKYLENE OXIDE, METHOD FOR PREPARATION THEREOF AND USE THEREOF
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1022300A1

  公开（公告）日：2000-07-26

  A resilient polyurethane foam produced by using a polyether polyol produced by reacting alkylene oxides with a polyhydroxy compound having at least 2 hydroxyl groups as an initiator in the presence of the catalyst for alkylene oxide ring-opening polymerization of the present invention, is excellent in foam physical properties, vibration characteristics and molding properties. The crushing property of a sheet cushion having a large size and a complicated shape will significantly be improved while maintaining comfortableness of the sheet cushion to sit on. Accordingly, a resilient polyurethane foam useful as a sheet cushion for vehicles, particularly for automobiles, can be provided. The present invention provides a catalyst for alkylene oxide ring-opening polymerization, which comprises a double metal cyanide complex obtained by having mono-tert-butyl ether of mono (or di or tri)ethylene glycol as an organic ligand coordinated to a reaction product obtained by reacting a metal halide with an alkali metal cyanometalate, in an aqueous medium. The present invention further provides a method for producing a resilient polyurethane foam, which comprises subjecting alkylene oxides including an alkylene oxide having a carbon number of at least 3, to ring-opening polymerization with a polyhydroxy compound having from 2 to 8 hydroxyl groups as an initiator in the presence of said catalyst for alkylene oxide ring-opening polymerization, and then reacting a polyether polyol having from 2 to 8 hydroxyl groups, a hydroxyl number of from 5 to 38 mgKOH/g and an oxyethylene group content of from 5 to 30 wt% and obtained by ring-opening polymerization of ethylene oxide in the presence of an alkali catalyst, with an isocyanate group-containing low molecular weight compound in the presence of a foaming agent.

  在本发明的环氧乙烷开环聚合催化剂存在下，使用由氧化亚烷与具有至少 2 个羟基的多羟基化合物反应生成的聚醚多元醇作为引发剂生产的弹性聚氨酯泡沫塑料，在泡沫塑料物理性能、振动特性和成型性能方面都非常出色。在保持片状坐垫舒适性的同时，还能显著改善具有较大尺寸和复杂形状的片状坐垫的挤压性能。因此，本发明提供了一种可用作车辆，特别是汽车坐垫的弹性聚氨酯泡沫塑料。 本发明提供了一种用于环氧烷开环聚合的催化剂，它包括一种双金属氰化物配合物，该配合物是由单(或二或三)乙二醇的单叔丁基醚作为有机配位体与金属卤化物与碱金属氰基金属酸盐在水介质中反应得到的反应产物配位而得到的。 本发明进一步提供了一种生产弹性聚氨酯泡沫的方法，该方法包括在所述环氧亚 烷开环聚合催化剂存在下，使包括碳数至少为 3 的环氧亚烷在内的氧化亚烷与具有 2 至 8 个羟基的多羟基化合物作为引发剂进行开环聚合、然后将具有 2 至 8 个羟基、羟基数为 5 至 38 mgKOH/g 和氧乙烯基含量为 5 至 30 wt%、在碱催化剂存在下通过环氧乙烷开环聚合反应得到的聚醚多元醇与含异氰酸酯基的低分子量化合物在发泡剂存在下进行反应。
• Dampening water composition for lithographic printing plate
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP1099566A1

  公开（公告）日：2001-05-16

  A dampening water composition for a lithographic printing plate comprising at least one compound represented by the following formula (I) and polyvinylpyrrolidone:         R1-O-(-CH2CH(CH3)-O-)m-H     (I) wherein R1 represents an alkyl group having carbon atoms of from 3 to 8, and m represents an integer ranging from 1 to 3. Said dampening water composition has a low dynamic surface tension and therefore exhibits favorable and stable printing properties under the conditions of members which rotate at high speed. Said dampening water composition exhibits stable printing properties to various ink compositions so as to obtain excellent printing matters.

  一种用于平版印刷板的润湿水组合物，由至少一种下式 (I) 所代表的化合物和聚乙烯吡咯烷酮组成： R1-O-(-CH2CH(CH3)-O-)m-H (I) 所述润湿水组合物具有较低的动态表面张力，因此在部件高速旋转的条件下具有良好和稳定的印刷性能。所述润湿水组合物对各种油墨组合物具有稳定的印刷性能，从而获得极佳的印刷效果。