ruthenium(III)Cl2(AsPh3)2(8-hydroxyquinolinato) | 139129-01-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: ruthenium(III)Cl2(AsPh3)2(8-hydroxyquinolinato)
• CAS: 139129-01-4
• 化学式: C₄₅H₃₆As₂Cl₂NORu
• 分子量: 928.606
• InChiKey: MRQATTFUQHWCBJ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  8-羟基喹啉 、 trichlorobis(triphenylarsine)(methanol)ruthenium(III) 以 甲醇 为溶剂， 生成 ruthenium(III)Cl2(AsPh3)2(8-hydroxyquinolinato)
  参考文献：
  名称：

  Complexes of ruthenium(II) and (III) derived from O,N-donor ligands, and their efficiency as catalytic oxidants for alcohols

  摘要：

  The new complexes [Ru(II)Cl2(PPh3)2L] (L = benzoic hydrazide, bhz; substituted derivatives, R-bhz; R = p-Cl, p-CH3, omicron-NH2 and phenylacetic hydrazide) and [Ru(III)X2 (AsPh3)2L'] (L' = monoanions of 8-hydroxyquinoline, 8-hq; omicron-aminophenol, 2-amino-3-hydroxypyridine; X = Cl or Br) have been isolated. They were characterized by spectroscopic techniques and their redox behaviour was studied by cyclic voltammetry. The ruthenium(III) complexes were found to be more effective catalysts than those of ruthenium(II) for the oxidation of primary alcohols to aldehydes and of secondary alcohols to ketones in the presence of N-methylmorpholine-N-oxide as co-oxidant. Turnovers reached 400 with the catalyst [Ru(III)Cl2(AsPh3)2(8-hq)].

  DOI：

  10.1016/s0277-5387(00)86133-1