[Ru(CO)2]2(μ-η(5),η(1)-C5H4)[μ-(CH3)2Si-(η(5)-C5H4)] | 178809-60-4

• 英文名称: [Ru(CO)2]2(μ-η(5),η(1)-C5H4)[μ-(CH3)2Si-(η(5)-C5H4)]
• CAS: 178809-60-4
• 化学式: C₁₆H₁₄O₄Ru₂Si
• 分子量: 500.51
• InChiKey: UOMITAXDVLBDQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(η5-C5H4)2(SiMe2)]Ru2(CO)4 以 氘代苯 为溶剂， 生成 [Ru(CO)2]2(μ-η(5),η(1)-C5H4)[μ-(CH3)2Si-(η(5)-C5H4)]
  参考文献：
  名称：

  Photoinduced rearrangements of ring-coupled bis(cyclopentadienylrutheniumdicarbonyl) compounds of the form Ru2(CO)4(η5,η5-C5H4LC5H4) (L  CHn2-, (CH3)2C-, C2H4- and (CH3)2S-) The molecular structure of [Ru(CO)2][Ru(CO)2Cl](η5,η5:η1-C5H4CH2C5H3)

  摘要：

  Compounds of the general form Ru-2(CO)(4)(eta(5),eta(5)-C(5)H(4)LC(5)H(4)), where L = CH2-, (CH3)(2)C-, C2H4- and (CH3)(2)Si-, have been found to undergo photolysis in deuterobenzene or deuterotoluene to give 'twisted' ruthenium hydride complexes of the form [Ru(CO)(2)][Ru(CO)(2)H](eta(5),eta(5):eta(1)-C(5)H(4)LC(5)H(3)). Reaction of these hydrides with chlorocarbons resulted in the formation of the corresponding chlorides which could be isolated and characterized by IR, H-1 and C-13 NMR, mass spectrometry, and elemental analysis. In the particular case of Ru-2(CO)(4)[eta(5),eta(5)-C5H4(CH3)(2)SiC5H4] a secondary photochemical reaction occurs with formation of [Ru(CO)(2)](2)(mu-eta(5):eta(1)-C5H4)[mu-(CH3)(2)Si-(eta(5)-C5H4)] in which Ru-Ru and Cp-Si bonds have been broken and new Ru-Cp and Ru-Si bonds formed. The molecular structure of [Ru(CO)(2)][RU(CO)(2)Cl](eta(5),eta(5):eta(1)-C5H4CH2C5H3) was determined by X-ray crystallography:monoclinic, Cc, a = 27.636(5) Angstrom, b = 9.058(2) Angstrom, c = 14.545(5) Angstrom, beta = 120.85(3)degrees, V = 3126(2) Angstrom(3), Z = 8, R(F)= 2.29%.

  DOI：

  10.1016/0022-328x(95)06018-r