2-azidoacetyl ferrocene | 256445-26-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-azidoacetyl ferrocene
• 英文别名: α-azidoacetylferrocene；2-azido-1-cyclopenta-1,4-dien-1-ylethanone;cyclopenta-1,3-diene;iron(2+)
• CAS: 256445-26-8
• 化学式: C₁₂H₁₁FeN₃O
• 分子量: 269.086
• InChiKey: NWXFPHGRQAAGTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-azidoacetyl ferrocene 、 1,3,5-苯三甲酰氯 在 三苯基膦 作用下， 以 乙醚 为溶剂， 以45%的产率得到1,3,5-tris(5-ferrocenyloxazol-2-yl)benzene
  参考文献：
  名称：

  Homotrimetallic Oxazolo-Ferrocene Complexes Displaying Tunable Cooperative Interactions between Metal Centers and Redox-Switchable Character

  摘要：

  A synthetic procedure based on the aza-Wittig reaction of alpha -azidoacetyl ferrocene or 1,1 ' -bis(alpha -azidoacetyl)ferrocene with-mono-, di-, and triacyl chlorides and triphenylphosphine has been developed to prepare the new homotrimetallic ferrocene Complexes 6, 9, and 10 containing at least two oxazole rings in the conjugation chain. Complexes 9 and 10 exhibited three and two reversible redox processes, respectively, indicating significant electrostatic interaction between the iron centers in these complexes. Protonation properties of complexes 9-13 have been assesed by use of H-1 NMR and cyclic voltammetry measurements.

  DOI：

  10.1021/om000604b