| 448299-18-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 448299-18-1
• 化学式: C₁₉H₃₄N₂O₂
• 分子量: 322.491
• InChiKey: PBDABZWOABZYSP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 nickel(II) acetate tetrahydrate 以 乙醇 、 水 为溶剂， 以76%的产率得到[4,4'-(1,9-nonanediamido-N,N'-diyl)bis(pent-3-en-2-one)-κ4-N,N',O,O']nickel(II)
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERISATION OF SOME NICKEL(II)β-KETOAMINES AND THEIR ADDUCTS WITH 2,2′-BIPYRIDINE AND 1,10-PHENANTHROLINE

  摘要：

  A series of nickel(11) beta-ketoimine complexes, {Ni[CH3C(O)CHC(CH3)NR](2), R = CH3, C4H9}, and ketoiminates, {Ni[CH3C(O)CH(CH3)C(-N(CH2)(n)N-)C(CH3)CHC(O)CH3], n = 2, 6, 8, 91, and their adducts with 2,2-bipyridine (bipy) and 1,10-phenanthroline (phen) have been synthesized and characterized using elemental analyses, magnetic susceptibility, conductivity, infrared and electronic spectral measurements. The ketoimine ligands coordinate to the nickel atom in a bidentate fashion using the N2O2 chromophore. A range of stereochemistries was observed for the nickel(II) ketoiminates from four-coordinate tetrahedral and square-planar geometry to six-coordinate octahedral geometry. Conductivity measurements indicate that the compounds are non-electrolytes. The influence of bridging chain lengthening on the adopted geometry is discussed and possible structures for the compounds are suggested.

  DOI：

  10.1081/sim-120004446