{NiCl2(thiourea)4} | 80374-80-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: {NiCl2(thiourea)4}
• CAS: 80374-80-7
• 化学式: C₄H₁₆Cl₂N₈NiS₄
• 分子量: 434.085
• InChiKey: RUMXCKAFCJPHHM-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  {NiCl2(thiourea)4} 在 NH₃ 作用下， 以 乙醇 、 水 为溶剂， 生成 {Ni(NH3)3(thiourea)3}Cl2*3thiourea
  参考文献：
  名称：

  Babaeva, A. V.; Ikramov, Kh. U.; Afanas'eva, G. G., Zhurnal Neorganicheskoi Khimii, 1963, vol. 8, p. 1078 - 1081

  摘要：

  DOI：
• 作为产物：
  描述：

  硫脲 、 nickel dichloride 以 乙醇 、 丙酮 为溶剂， 生成 {NiCl2(thiourea)4}
  参考文献：
  名称：

  Patel, R. N.; Ramana Rao, D. V., Indian Journal of Chemistry, 1966, vol. 4, p. 44 - 45

  摘要：

  DOI：

文献信息

• Infra-red absorption spectra of complexes of thiourea
  作者：K. Swaminathan、H.M.N.H. Irving

  DOI：10.1016/0022-1902(64)80212-8

  日期：1964.7

  The infra-red absorption spectra of complexes of thiourea with manganese, cobalt, nickel, zinc, copper, mercury, cadmium and lead have been interpreted to show the existence of metal to sulphur bond only rather than metal to nitrogen bond.

  硫脲与锰，钴，镍，锌，铜，汞，镉和铅的配合物的红外吸收光谱已被解释为表明仅存在金属与硫键而不是金属与氮键的存在。
• A thermal decomposition study of some nickel(II)thioureachloride complexes
  作者：M. P. B. Attard、J. O. Hill、R. J. Magee、S. Prakash、M. N. Sastri

  DOI：10.1007/bf01911073

  日期：1986.3
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 8.16, page 1009 - 1019
  作者：

  DOI：——

  日期：——
• Shape and phase evolution of nickel sulfide nano/microcrystallines via a facile way
  作者：Peng-Fei Yin、Chao Zhou、Xiang-Yu Han、Zheng-Ren Zhang、Chuan-Hui Xia、Li-Li Sun

  DOI：10.1016/j.jallcom.2014.09.113

  日期：2015.1

  Nickel sulfides nano/microcrystallines were synthesized through a facile and efficient single-source method by thermal decomposition the precursor of tetrakis thiourea nickel chloride crystals ( TTNC) complex in a Teflon-lined autoclave. It is found that the reaction temperature, reaction time and relative reaction pressure have important influence on morphology of the final products and pure Ni3S4 can be transformed to NiS2 by increasing the thermal decomposition temperature from 200 degrees C to 250 degrees C under sealed conditions. Meanwhile, infrared absorption, Raman spectrums and magnetic properties of as-prepared cubic Ni3S4 and NiS2 were investigated. (C) 2014 Elsevier B.V. All rights reserved.
• Field‐induced magnetic ordering in uniaxial nickel systems: A second example
  作者：Armando Paduan‐Filho、Robert D. Chirico、K. O. Joung、Richard L. Carlin

  DOI：10.1063/1.441589

  日期：1981.4

  The zero-field susceptibilities parallel and perpendicular to the tetragonal axis of NiCl2⋅4SC(NH2)2 have been measured between 1.2 and 30 K and fitted to the usual spin Hamiltonian. The resulting parameters are D/kB = 7.6±0.4 K, z0J/kB = −4.5±0.3 K, g∥ = 2.26±0.03 and g⊥ = 2.34±0.03. The susceptibility has also been measured parallel to the tetragonal axis at constant temperatures between 0.3 and 2 K as a function of external field. Magnetic ordering is found to occur, and portions of the phase boundary between paramagnetic and antiferromagnetic states have been determined.