5-chloro-2,3-dihydrothieno[3,4-b][1,4]dioxine | 1409917-53-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-chloro-2,3-dihydrothieno[3,4-b][1,4]dioxine
• CAS: 1409917-53-8
• 化学式: C₆H₅ClO₂S
• 分子量: 176.624
• InChiKey: HNHTYUVLSHVXGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  46.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,5-二氯-3,4-乙烯基二氧噻吩 在 正丁基锂 、 水 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 0.5h， 以51%的产率得到5-chloro-2,3-dihydrothieno[3,4-b][1,4]dioxine
  参考文献：
  名称：

  Chain-Growth Polymerization of 2-Chlorothiophenes Promoted by Lewis Acids

  摘要：

  Lewis acids promote the polymerization of several 2-chloroalkylenedioxythiophenes, providing high-molecular-weight conjugated polymers. The proposed mechanism is a cationic chain-growth polymerization, as confirmed by end-capping reactions and a linear correlation of molecular weight with percent conversion. The "living" character of this process was used to prepare new block copolymers.

  DOI：

  10.1021/ja308498h

文献信息

• ELECTROCHROMIC POLYMER AND ELECTROCHROMIC DEVICES CONTAINING THE SAME
  申请人：AMBILIGHT INC.

  公开号：US20220403100A1

  公开（公告）日：2022-12-22

  A method for forming an electrochromic polymer block includes: forming each of reaction units by reacting two or more electron-donor groups, wherein each of the reaction units includes (i) a first backbone formed by the two or more electron-donor groups and (ii) at least one reactive functional group connected to each end of the first backbone; and forming the electrochromic polymer block by reacting at least two of the reaction units with acid-catalyzed cationic polymerization, wherein the electrochromic polymer block includes a second backbone formed by two or more of the first backbones.