cadmium(II) 5-((2-oxocyclohexylidene)amino)quinolin-8-olate chloride hydrate | 143933-62-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: cadmium(II) 5-((2-oxocyclohexylidene)amino)quinolin-8-olate chloride hydrate
• CAS: 143933-62-4
• 化学式: C₁₅H₁₃N₂O₂*Cd*Cl*H₂O
• 分子量: 419.159
• InChiKey: QVOAGKBWQIKTFU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.3
• 重原子数：
  22.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  96.88
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  5-(2-oxocycloheximino)-8-hydroxyquinoline 、 cadmium(II) chloride 以 乙醇 为溶剂， 以47%的产率得到cadmium(II) 5-((2-oxocyclohexylidene)amino)quinolin-8-olate chloride hydrate
  参考文献：
  名称：

  Carbonyl-bridged polymeric metal chelates of some quinolinol-containing 2-iminoketones

  摘要：

  Four-coordinate copper(II), nickel(II), cobalt(II) and cadmium(II) complexes formed by reaction of 8-hydroxyquinoline-5-iminoketones with M(II) chloride are described. Characterization of the isolated complexes has been performed on the basis of elemental and thermal analyses, electronic and IR spectral data as well as conductivity measurements. The ligands were found to act as monobasic bidentate N,O chelating agents. It is proposed that the complexes are polymeric with intermolecular carbonyl bridging. Tetrahedral or square planar stereochemical configuration is suggested for these complexes.

  DOI：

  10.1016/s0277-5387(00)83365-3