cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(OC(O)CF3)] | 727730-66-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(OC(O)CF3)]
• CAS: 727730-66-7
• 化学式: C₄H₁₂N*C₂₀H₁₈F₃N₄O₁₆Pt
• 分子量: 896.601
• InChiKey: GHYLYSDBMJRNIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  以 二氯甲烷 、 丙酮 为溶剂， 生成 cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)(OC(O)CF3)]
  参考文献：
  名称：

  Bis(2,6-dinitroaryl)platinum Complexes. 1. Synthesis through Transmetalation Reactions

  摘要：

  Complexes CiS-Q[Pt(kappa(2)-Ar)(kappa(1)-Ar)Cl] [Q = Ph3PCH2Ph (1), Me4N (2); kappa(2)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5-kappa(2)-C,O; kappa(1)-Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5- kappa(1)-C] have been prepared by reacting [HgAr2] [Ar = C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5] and Q(2)[Pt2Cl6] (4:1) in acetone at 100 degreesC. Complex 2 could be prepared by reacting [HgAr2] (i) with [Me4N](2)[Pt2Cl6] (2:1) in the presence of an excess of [Me4N]Cl or (ii) with [Me4N](2)[PtCl4] (1:1). The reaction of equimolecular amounts of 2 and Tl(acac) or AgClO4 gave, respectively, cis-Me4N[Pt(kappa(1)-Ar)(2)(acaC-kappa(2_)O,O)] (3) or cis-[Pt(kappa(2)-Ar)(kappa(1)-Ar)(OH2)] (4), which in turn reacts with neutral ligands to give cis-[Pt(kappa(2)-Ar)- (kappa(1)-Ar)L] [L = PhCN (5), tetrahydrothiophene (6)]. Hg(O2CCF3)(2) reacts with an equimolar amount of 2 to give cis-Me4N[Pt(kappa(2)-Ar)(kappa(1)-Ar){OC(O)CF3}] (7). The structures of complexes 1, 4.Et2O, 4.CH2Cl2, and 7 have been solved by X-ray diffraction studies.

  DOI：

  10.1021/om049801r