| 1232361-16-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1232361-16-8
• 化学式: C₄₂H₅₀N₂O₁₂
• 分子量: 774.865
• InChiKey: VZGRHAKJSCVFSK-VGFSZAGXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  56.0
• 可旋转键数：
  0.0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  135.48
• 氢给体数：
  0.0
• 氢受体数：
  14.0

反应信息

• 作为反应物：
  描述：

  反应 0.17h， 生成
  参考文献：
  名称：

  Photoresponsive Host−Guest Systems Based on a New Azobenzene-Containing Crytpand

  摘要：

  A new azobenzene-bridged cryptand was synthesized; it can be well controlled between cis and trans isomers by irradiation with different wavelengths or by being heated. It was found that this cryptand exhibits an ON-OFF binding ability with 2,7-diazapyrenium (DAP) derivatives. It binds DAP derivatives as the cis isomer only, as demonstrated by various methods. The fluorescence property of DAP derivatives endows these host guest systems with detectable fluorescent output signals, which makes monitoring these photoresponsive systems convenient.

  DOI：

  10.1021/ol100770j
• 作为产物：
  描述：

  以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Photoresponsive Host−Guest Systems Based on a New Azobenzene-Containing Crytpand

  摘要：

  A new azobenzene-bridged cryptand was synthesized; it can be well controlled between cis and trans isomers by irradiation with different wavelengths or by being heated. It was found that this cryptand exhibits an ON-OFF binding ability with 2,7-diazapyrenium (DAP) derivatives. It binds DAP derivatives as the cis isomer only, as demonstrated by various methods. The fluorescence property of DAP derivatives endows these host guest systems with detectable fluorescent output signals, which makes monitoring these photoresponsive systems convenient.

  DOI：

  10.1021/ol100770j