5,5'-((ethane-1,2-diylbis(methylazanediyl))bis(methylene))bis(6-hydroxy-2,3-dimethylbenzaldehyde) | 1396809-62-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,5'-((ethane-1,2-diylbis(methylazanediyl))bis(methylene))bis(6-hydroxy-2,3-dimethylbenzaldehyde)
• CAS: 1396809-62-3
• 化学式: C₂₄H₃₂N₂O₄
• 分子量: 412.529
• InChiKey: IOEWVXKTNLIRPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.52
• 重原子数：
  30.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  81.08
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  5,5'-((ethane-1,2-diylbis(methylazanediyl))bis(methylene))bis(6-hydroxy-2,3-dimethylbenzaldehyde) 、 1,1,3,3-bis[spiro-2',2''-dioxy-1',1''-biphenyl]-5,5-bis(1-methylhydrazido)-1,3,5,2,4,6-cyclotriphosphazene 以 甲醇 、 氯仿 为溶剂， 反应 5.0h， 以75%的产率得到
  参考文献：
  名称：

  Synthesis and spectral characterization of cyclotriphosphazene based 18-membered macrocycles

  摘要：

  New 18-membered cyclotriphosphazene-containing macrocycles 7-10 were obtained by 1 + 1 condensation reaction of [dispiro-N3P3(C12H8O2)(2)((N(Me)N=CH)(2) N4C20H26)] (2) with N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4-methyl-2-formylphenol) (3), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4,5-dimethyl-2-formylphenol) (4), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-chloro-2-formylphenol) (5) and N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-bromo-2-formylphenol) (6), respectively. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.016
• 作为产物：
  描述：

  聚合甲醛 、 2-hydroxy-5,6-dimethylbenzaldehyde 、 N,N'-二甲基乙二胺 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 36.0h， 以80%的产率得到5,5'-((ethane-1,2-diylbis(methylazanediyl))bis(methylene))bis(6-hydroxy-2,3-dimethylbenzaldehyde)
  参考文献：
  名称：

  Synthesis and spectral characterization of cyclotriphosphazene based 18-membered macrocycles

  摘要：

  New 18-membered cyclotriphosphazene-containing macrocycles 7-10 were obtained by 1 + 1 condensation reaction of [dispiro-N3P3(C12H8O2)(2)((N(Me)N=CH)(2) N4C20H26)] (2) with N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4-methyl-2-formylphenol) (3), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4,5-dimethyl-2-formylphenol) (4), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-chloro-2-formylphenol) (5) and N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-bromo-2-formylphenol) (6), respectively. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.016