lithium succinamate | 667871-86-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: lithium succinamate
• CAS: 667871-86-5
• 化学式: C₄H₆NO₃*Li
• 分子量: 123.038
• InChiKey: KSXYULUMXOFVLE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -4.99
• 重原子数：
  9.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  83.22
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  lithium succinamate 在 calcium(II) nitrate tetrahydrate 作用下， 以 乙醇 、 水 为溶剂， 以0.011 g的产率得到succinamic acid ; calcium salt
  参考文献：
  名称：

  Synthesis, crystal structures and spectroscopic studies of calcium(II) succinamate(-1) complexes

  摘要：

  The reaction of succinamic acid (H(2)sucm) with Ca(NO3)(2)center dot 4H(2)O yielded compounds [Ca(Hsucm)(NO3) (H2O)](n) (1) and [Ca(Hsucm)(2)] (2). The succinamate(-1) ligand presents two new ligation modes and coordinates through the two carboxylato and the amide O-atoms, thus bridging three Ca-II ions which assemble into zig-zag 1D chains in 1 and 2D networks in 2. Intermolecular hydrogen bonding interactions in the crystal structures of 1 and 2 result in overall 3D framework structures. Both compounds have been characterized by IR and H-1 NMR spectroscopy, and their thermal decomposition was monitored by TG/DTG and DSC measurements. The structural comparison of 1 and 2 with known lanthanide(III) succinamate(-1) complexes reveals differences in the coordination mode of the ligand and in the coordination number of the metal ions; the biological relevance of these differences is discussed. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.04.021
• 作为产物：
  描述：

  丁酰胺酸 在 lithium hydroxide monohydrate 作用下， 以 乙醇 、 水 为溶剂， 生成 lithium succinamate
  参考文献：
  名称：

  Synthesis, crystal structures and spectroscopic studies of calcium(II) succinamate(-1) complexes

  摘要：

  The reaction of succinamic acid (H(2)sucm) with Ca(NO3)(2)center dot 4H(2)O yielded compounds [Ca(Hsucm)(NO3) (H2O)](n) (1) and [Ca(Hsucm)(2)] (2). The succinamate(-1) ligand presents two new ligation modes and coordinates through the two carboxylato and the amide O-atoms, thus bridging three Ca-II ions which assemble into zig-zag 1D chains in 1 and 2D networks in 2. Intermolecular hydrogen bonding interactions in the crystal structures of 1 and 2 result in overall 3D framework structures. Both compounds have been characterized by IR and H-1 NMR spectroscopy, and their thermal decomposition was monitored by TG/DTG and DSC measurements. The structural comparison of 1 and 2 with known lanthanide(III) succinamate(-1) complexes reveals differences in the coordination mode of the ligand and in the coordination number of the metal ions; the biological relevance of these differences is discussed. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.04.021

文献信息

• The succinamate(−1) ligand in 4f-metal chemistry: First example of amide coordination in the double-chain 1D coordination polymer catena-aquatris(succinamato(−1))erbium(III)
  作者：Argyro Messimeri、Vassilios Nastopoulos、Aris Terzis、Catherine P. Raptopoulou、Christos Papadimitriou、Spyros P. Perlepes

  DOI：10.1016/j.inoche.2005.03.017

  日期：2005.6

  Two new 1D lanthanide(III) coordination polymers are reported which feature succinamate(- 1) ligands (LH-) that exhibit three different coordination modes. Compound (1)(infinity)[Er(LH)(3)(HO)] (1), which has been structurally characterized by single-crystal X-ray crystallography, is the first binary metal/LH- complex, the first example of a succinamato(- 1) metal complex in which amide coordination of LH- is realized and the first example of a polymeric LH- complex of any metal. The erbium(III) compound and its holmium(III) analog 2 have been studied by a variety of physical and spectroscopic techniques. (C) 2005 Elsevier B.V. All rights reserved.