3-(2,2-Dimethyl-3-(prop-2-yn-1-yloxy)propoxy)prop-1-yne | 1428736-76-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(2,2-Dimethyl-3-(prop-2-yn-1-yloxy)propoxy)prop-1-yne
• 英文别名: 2,2-dimethyl-1,3-bis(prop-2-ynoxy)propane
• CAS: 1428736-76-8
• 化学式: C₁₁H₁₆O₂
• 分子量: 180.247
• InChiKey: NJBJGXQVJOJPJJ-UHFFFAOYSA-N

物化性质

• 沸点：
  233.2±25.0 °C(Predicted)
• 密度：
  0.946±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,2-二甲基-1,3-丙二醇 、 3-溴丙炔 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以50%的产率得到3-(2,2-Dimethyl-3-(prop-2-yn-1-yloxy)propoxy)prop-1-yne
  参考文献：
  名称：

  金属有机骨架中固定单体和移动单体之间的逐步增长共聚

  摘要：

  证明了固定在结晶态的单体与在溶液状态下可移动的单体之间的A–A / B–B逐步生长共聚。两种单体之一固定为金属-有机骨架（MOF）的有机配体，并与可移动的客体单体聚合，从而形成线性聚合物。聚合行为与溶液聚合完全不同。特别地，取决于MOF结构，聚合度（DP）收敛至特定值。不可避免的终止不是由于聚合反应的不完全，而是由于在几种相邻的固定单体中选择了两种聚合配偶体。基于聚合机理的蒙特卡洛模拟完全支持了这一点。

  DOI：

  10.1002/anie.201901308

文献信息

• PROCESSES FOR PREPARING CURED FILMS, THE RESULTING FILMS, AND PLASMA-INITIATED POLYMERIZABLE COMPOSITIONS
  申请人：FUJIFILM Corporation

  公开号：US20140170405A1

  公开（公告）日：2014-06-19

  Provided are novel plasma-assisted processes for preparing cured films having excellent heat resistance and moisture resistance. A process for preparing a cured film, comprising at least: applying a composition containing (A) at least one conductive polymer precursor on a substrate to form a coating layer, and irradiating the coating layer with a plasma to polymerize the conductive polymer precursor (A).

  提供了一种新型等离子体辅助制备固化膜的工艺，该固化膜具有优异的耐热性和耐潮性。一种制备固化膜的工艺，包括至少以下步骤：在基板上涂布含有（A）至少一种导电聚合物前体的组合物以形成涂层层，然后用等离子体照射涂层层以聚合导电聚合物前体（A）。
• Curable resin composition
  申请人：NIPPON PAINT COMPANY LIMITED

  公开号：EP0534465A2

  公开（公告）日：1993-03-31

  A curable resin composition comprising (a) an acrylic, polyester, epoxy or polyol resin having a plurality of alkynyl groups, (b) an organohydrogenpolysiloxane, and (c) an amount of platinum catalyst effective to catalyze the cross link reaction between (a) and (b). The composition is useful for coating and molding purposes and gives a cured product having excellent acid resistance, water resistance and other properties.

  一种可固化的树脂组合物，包括：(a) 具有多个炔基的丙烯酸、聚酯、环氧或多元醇树脂；(b) 有机氢聚硅氧烷；(c) 一定量的铂催化剂，能有效催化(a)和(b)之间的交联反应。该组合物可用于涂层和模塑，固化后的产品具有优异的耐酸性、耐水性和其他性能。
• Transformation of Metal–Organic Framework to Polymer Gel by Cross-Linking the Organic Ligands Preorganized in Metal–Organic Framework
  作者：Takumi Ishiwata、Yuki Furukawa、Kouta Sugikawa、Kenta Kokado、Kazuki Sada

  DOI：10.1021/ja3125614

  日期：2013.4.10

  Until now, seamless fusion of metal organic frameworks (MOFs) and covalently cross-linked polymer gels (PG) at molecular level has been extremely rare, since these two matters have been regarded as opposite, that is, hard versus soft. In this report, we demonstrate transformation of cubic MOF crystals to PG via inner cross-linking of the organic linkers in the void space of MOF, followed by decomposition of the metal coordination. The obtained PG behaved as a polyelectrolyte gel, indicating the high content of ionic groups inside. Metal ions were well adsorbed in the PG due to its densely packed carboxylate groups. A chimera-type hybrid material consisting of MOF and PG was obtained by partial hydrolysis of resulting cross-linked MOF. The shape of resulting PG network well reflected the crystal structure of MOF employed as a template. Our results will connect the two different network materials that have been ever studied in the two different fields to provide new soft and hard hybrid materials, and the unique copolymerization in the large void space of the MOF will open a new horizon toward "ideal network polymers" never prepared before now.
• DENDRI-TAC AND THEIR USE AS THERANOSTICS
  申请人：UNIVERSITE D'AVIGNON ET DES PAYS DU VAUCLUSE

  公开号：US20180126011A1

  公开（公告）日：2018-05-10

  The present invention relates to novel amphiphilic dendrimers, hereafter denoted Dendri-TAC. The present invention also relates to perfluorocarbon nanoemulsions stabilized by these amphiphilic dendrimers and their uses for in vivo diagnostic and/or for therapy, notably as theranostic tools, for detection and/or treatment of cancer.
• US5324807A
  申请人：——

  公开号：US5324807A

  公开（公告）日：1994-06-28