1-iodo-3,3-(ethylenedioxy)-nonane | 936013-06-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-iodo-3,3-(ethylenedioxy)-nonane
• 英文别名: 2-Hexyl-2-(2-iodoethyl)-1,3-dioxolane
• CAS: 936013-06-8
• 化学式: C₁₁H₂₁IO₂
• 分子量: 312.191
• InChiKey: OFCMVWLRKNOWOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-iodo-3,3-(ethylenedioxy)-nonane 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 2.5h， 以72%的产率得到1-cyano-1-(trans-4-methoxycyclohexyl)-4,4-(ethylenedioxy)-decane
  参考文献：
  名称：

  US2007/108410

  摘要：

  公开号：

文献信息

• Liquid crystal compound having lactone ring, liquid crystal composition, and liquid crystal display device
  申请人：Goto Mayumi

  公开号：US20070108410A1

  公开（公告）日：2007-05-17

  A nematic liquid crystal compound represented by any one of formulas (a-1) to (a-6): in formulas (a-1) to (a-6), Ra and Rb are each independently hydrogen or alkyl having 1 to 10 carbons, provided that in the alkyl, —CH2- may be replaced by —O—, —(CH2)2- may be replaced by —CH═CH—, and hydrogen may be replaced by a halogen; ring A1 and ring A2 are each independently trans-1,4-cyclohexylene or 1,4-phenylene, provided that in these rings hydrogen may be replaced by a halogen, and in the case where the ring is trans-1,4-cyclohexylene, —CH2- may be replaced by —O—, and —CH2CH— may be replaced by —CH═C—; and Z1 and Z2 are each independently a single bond, —COO—, —OCO—, —OCH2-, —CH2O— or —CH2CH2-, provided that in formula (a-3), in the case where ring A2 is trans-1,4-cyclohexylene, Z2 is a single bond, —COO—, —OCO—, —OCH2- or —CH2O—, in the case where Ra is —C3H7, Rb is —OC2H5, and Z2 is a single bond, ring A2 is trans-1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 2-fluoro-3-chloro-1,4-phenylene, 2-chloro-3-fluoro-1,4-phenylene or 2,3-dichloro-1,4-phenylene, and in formula (a-4), in the case where ring A1 is trans-1,4-cyclohexylene, Z1 is a single bond, —COO—, —OCO—, —OCH2O—.

  任何一个式子(a-1)到(a-6)所代表的向列相液晶化合物： 在式子(a-1)到(a-6)中，Ra和Rb各自独立地代表氢或有1到10个碳的烷基，其中在烷基中，-CH2-可以被- O-代替，-( )2-可以被-CH═CH-代替，氢可以被卤素代替；环A1和环A2各自独立地代表反式1,4-环己烷基或1,4-苯基，其中在这些环中，氢可以被卤素代替，在环为反式1,4-环己烷基的情况下，- -可以被-O-代替，而- CH-可以被-CH═C-代替；Z1和Z2各自独立地代表单键，-COO-，-OCO-，-O -，- O-或- -，其中在式子(a-3)中，在环A2为反式1,4-环己烷基的情况下，Z2为单键，-COO-，-OCO-，-O -或- O-，在Ra为-C3H7，Rb为-OC2H5，且Z2为单键的情况下，环A2为反式1,4-环己烷基，1,3-二氧六环基，2-氟-1,4-苯基，3-氟-1,4-苯基，2-氟-3-氯-1,4-苯基，2-氯-3-氟-1,4-苯基或2,3-二氯-1,4-苯基，在式子(a-4)中，在环A1为反式1,4-环己烷基的情况下，Z1为单键，-COO-，-OCO-，-O O-。
• Liquid Crystal Compound Having Lactone Ring, Liquid Crystal Composition, And Liquid Crystal Display Device
  申请人：GOTO Mayumi

  公开号：US20100038588A1

  公开（公告）日：2010-02-18

  A nematic liquid crystal compound represented by any one of formulas (a-1) to (a-6): in formulas (a-1) to (a-6), Ra and Rb are each independently hydrogen or alkyl having 1 to 10 carbons, provided that in the alkyl, —CH2- may be replaced by —O—, —(CH2)2- may be replaced by —CH═CH—, and hydrogen may be replaced by a halogen; ring A1 and ring A2 are each independently trans-1,4-cyclohexylene or 1,4-phenylene, provided that in these rings hydrogen may be replaced by a halogen, and in the case where the ring is trans-1,4-cyclohexylene, —CH2- may be replaced by —O—, and —CH2CH— may be replaced by —CH═C—; and Z1 and Z2 are each independently a single bond, —COO—, —OCO—, —OCH2-, —CH2O— or —CH2CH2-, provided that in formula (a-3), in the case where ring A2 is trans-1,4-cyclohexylene, Z2 is a single bond, —COO—, —OCO—, —OCH2- or —CH2O—, in the case where Ra is —C3H7, Rb is —OC2H5, and Z2 is a single bond, ring A2 is trans-1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 2-fluoro- 1,4 -phenylene, 3-fluoro-1,4-phenylene, 2-fluoro-3-chloro-1,4-phenylene, 2-chloro- 3 -fluoro-3,4-phenylene or 2,3-dichloro-1,4-phenylene, and in formula (a-4), in the case where ring A1 is trans-1,4-cyclohexylene, Z1 is a single bond, —COO—, —OCO—, —OCH2- or —CH2O—.

  任意一种由公式(a-1)到(a-6)中的任意一种表示的向列相液晶化合物:在公式(a-1)到(a-6)中，Ra和Rb分别独立地表示氢或具有1到10个碳的烷基，但在烷基中，—CH2-可以被—O—替换，—( )2-可以被—CH═CH—替换，并且氢可以被卤素替换;环A1和环A2分别独立地表示反式1,4-环己烯基或1,4-苯基，但在这些环中氢可以被卤素替换，在环为反式1,4-环己烯基的情况下，— -可以被—O—替换，— CH—可以被—CH═C—替换;Z1和Z2分别独立地表示单键、—COO—、—OCO—、—O -、— O—或— -，但在公式(a-3)中，在环A2为反式1,4-环己烯基的情况下，Z2为单键、—COO—、—OCO—、—O -或— O—，在Ra为—C3H7，Rb为—OC2H5，Z2为单键，环A2为反式1,4-环己烯基，1,3-二氧杂环戊烷-2,5-二基，2-氟-1,4-苯基，3-氟-1,4-苯基，2-氟-3-氯-1,4-苯基，2,3-二氯-1,4-苯基，在公式(a-4)中，在环A1为反式1,4-环己烯基的情况下，Z1为单键、—COO—、—OCO—、—O -或— O—。
• US7618688B2
  申请人：——

  公开号：US7618688B2

  公开（公告）日：2009-11-17
• US7875327B2
  申请人：——

  公开号：US7875327B2

  公开（公告）日：2011-01-25