ethyl 3-(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2-carboxylate | 591733-24-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: ethyl 3-(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2-carboxylate
• 英文别名: 3-Trifluoromethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester
• CAS: 591733-24-3
• 化学式: C₁₁H₁₃F₃O₂
• 分子量: 234.218
• InChiKey: ZKWKAVRFAULGRT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  ethyl 3-(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2-carboxylate 、 (三氟甲基)三甲基硅烷 在 四丁基氟化铵 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 反应 15.0h， 生成 2,2,2-Trifluoro-1-[3-(trifluoromethyl)-2-bicyclo[2.2.1]hept-5-enyl]ethanone
  参考文献：
  名称：

  [EN] FLUORINATED POLYMERS
  [FR] POLYMERES FLUORES

  摘要：

  公开号：

  WO2004041760A3
• 作为产物：
  描述：

  4,4,4-三氟巴豆酸乙酯 、 环戊二烯 生成 ethyl 3-(trifluoromethyl)bicyclo[2.2.1]hept-5-ene-2-carboxylate
  参考文献：
  名称：

  Stereochemistry of the Diels-Alder reaction. V. Fluorinated trans-olefinic acids and derivatives with cyclopentadiene

  摘要：

  DOI：

  10.1021/jo00944a002

文献信息

• Monomers for photoresists bearing acid-labile groups of reduced optical density
  申请人：Puy Van Der Michael

  公开号：US20060008730A1

  公开（公告）日：2006-01-12

  Monomers and polymers useful for forming photoresists are provided. More particularly, photoresists, as well as monomers and polymers for photoresists useful in micro-lithography, specifically monomers bearing acid-labile groups of reduced optical density. The resulting photoresists exhibit improved transparency to 157 nm light. The photoresist compositions are composed of a mixture of at least one water insoluble, acid decomposable polymer which is prepared from at least one monomeric unit which comprises an acid labile group of the formula —OC(CH 3 ) 2 CF 3 and which is substantially transparent to ultraviolet radiation at a wavelength of about 157 nm and at least one photoacid generator capable of generating an acid upon exposure to sufficient activating energy at a wavelength of about 157 nm.

  提供用于形成光刻胶的单体和聚合物。更具体地说，提供了用于微影的光刻胶、单体和聚合物，特别是具有降低光密度的酸敏基团的单体。由此产生的光刻胶在157nm光下具有改善的透明度。光刻胶组合物由至少一种不溶于水的酸分解聚合物混合而成，该聚合物是由至少一种含有公式—OC（CH3）2CF3的酸敏基团的单体单元制备而成，并且在约157nm的紫外辐射下具有相当的透明度，以及至少一种光酸发生剂，能够在约157nm的激活能量下产生酸。
• Fluorinated molecules and methods of making and using same
  申请人：——

  公开号：US20030232276A1

  公开（公告）日：2003-12-18

  Provided are polymers derived from fluoroalkyl norbornenes, fluorinated crotonates, fluorinated allyl alcohols, and combinations of two or more thereof for use in a wide variety of applications, including photoresist compositions. Also provided are methods for producing the fluoroalkyl norbornenes, fluorinated crotonates, and fluorinated allyl alcohols for use in the present polymers.

  本发明提供了由氟烷基降冰片烯、氟化巴豆酸盐、氟化烯丙基醇以及其中两种或两种以上的组合物衍生的聚合物，可用于多种应用领域，包括光刻胶组合物。此外，还提供了用于本聚合物的氟烷基降冰片烯、氟化巴豆酸盐和氟化烯丙基醇的生产方法。
• Fluorinated polymers
  申请人：Honeywell International Inc.

  公开号：US20040091813A1

  公开（公告）日：2004-05-13

  Provided are compounds described by the formula: 1 wherein W, X, Y, and Z are independently selected from the group consisting of hydrogen, fluorine, hydroxyl, substituted alkyl and unsubstituted alkyl. Also provided are methods of making compounds of the present invention, and polymers derived from one or more compounds of the present invention.

  所提供的是由式 1 所描述的化合物： 1 其中 W、X、Y 和 Z 独立地选自氢、氟、羟基、取代烷基和未取代烷基组成的组。还提供了制造本发明化合物的方法，以及由一种或多种本发明化合物衍生的聚合物。
• FLUORINATED MOLECULES AND METHODS OF MAKING AND USING SAME
  申请人：Honeywell International Inc.

  公开号：EP1476788A2

  公开（公告）日：2004-11-17
• [EN] FLUORINATED MOLECULES AND METHODS OF MAKING AND USING SAME<br/>[FR] MOLECULES FLUOREES ET LEURS PROCEDES DE FABRICATION ET D'UTILISATION
  申请人：HONEYWELL INT INC

  公开号：WO2003073169A2

  公开（公告）日：2003-09-04

  Provided are polymers derived from fluoroalkyl norbornenes, fluorinated crotonates, fluorinated allyl alcohols, and combinations of two or more thereof for use in a wide variety of applications, including photoresist compositions. Also provided are methods for producing the fluoroalkyl norbornenes, fluorinated crotonates, and fluorinated allyl alcohols for use in the present polymers.