copper(II)(1-diethylamino-2-methyl-2-propanol(1-))2 | 581099-12-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: copper(II)(1-diethylamino-2-methyl-2-propanol(1-))2
• 英文别名: bis(diethylamino-2-methyl-2-propoxy)copper(II)；copper;1-(diethylamino)-2-methylpropan-2-olate
• CAS: 581099-12-9
• 化学式: C₁₆H₃₆CuN₂O₂
• 分子量: 352.02
• InChiKey: POTMQNYSPRZPJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  copper(II)(1-diethylamino-2-methyl-2-propanol(1-))2 以 neat (no solvent) 为溶剂， 生成 铜
  参考文献：
  名称：

  Synthesis of Cu(II) aminoalkoxide complexes and their unusual thermolysis to Cu(0)

  摘要：

  The "fluorine free" Cu(II) aminoalkoxide complexes Cu(OCMe2CH2NR2)(2) (R = Me(I), Et(II)) are synthesized and characterized as a low melting solid (I) and a viscous liquid (II). The complexes are thermally decomposed at below 200degreesC to produce metallic copper by unusual gamma-hydrogen elimination reaction. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.12.022
• 作为产物：
  描述：

  1-diethylmethylamino-2-methyl-2-propanol 、 copper(II) methoxide 以 甲苯 为溶剂， 以61.4%的产率得到copper(II)(1-diethylamino-2-methyl-2-propanol(1-))2
  参考文献：
  名称：

  Synthesis of Cu(II) aminoalkoxide complexes and their unusual thermolysis to Cu(0)

  摘要：

  The "fluorine free" Cu(II) aminoalkoxide complexes Cu(OCMe2CH2NR2)(2) (R = Me(I), Et(II)) are synthesized and characterized as a low melting solid (I) and a viscous liquid (II). The complexes are thermally decomposed at below 200degreesC to produce metallic copper by unusual gamma-hydrogen elimination reaction. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.12.022

文献信息

• Volatile copper aminoalkoxide complex and deposition of copper thin film using same
  申请人：Korea Research Institute of Chemical Technology

  公开号：US06982341B1

  公开（公告）日：2006-01-03

  A volatile copper aminoalkoxide complex of formula (I) can form a copper thin film having an improved quality by metal organic chemical vapor deposition (MOCVD): wherein, R1, R2, R3 and R4 are each independently C1-4 alkyl optionally carrying one or more fluorine substituents; and m is an integer in the range of 1 to 3.

  一种具有改进质量的铜氨基烷氧化物复合物（I）可通过金属有机化学气相沉积（MOCVD）形成铜薄膜：其中，R1、R2、R3和R4分别独立地是C1-4烷基，可选择地携带一个或多个氟取代基；m是在1到3范围内的整数。