(5,10,15-triphenyl-2:3,7:8,12:13,17:18-tetrabutanocorrolato)copper | 1287673-74-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (5,10,15-triphenyl-2:3,7:8,12:13,17:18-tetrabutanocorrolato)copper
• CAS: 1287673-74-8
• 化学式: C₅₃H₄₇CuN₄
• 分子量: 803.529
• InChiKey: AQASIGQHFKOSAK-LORVUSROSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (5,10,15-triphenyl-2:3,7:8,12:13,17:18-tetrabutanocorrolato)copper 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 甲苯 为溶剂， 反应 0.17h， 以77%的产率得到(5,10,15-triphenyl-2:3,7:8,12:13,17:18-tetrabenzocorrolato)copper
  参考文献：
  名称：

  Synthetic Routes to 5,10,15-Triaryl-tetrabenzocorroles

  摘要：

  Two different synthetic routes for the preparation of 5,10,15-triaryl-tetrabenzocorroles have been developed. The first approach is based on the condensation of a tetrahydroisoindole with aryl-aldehydes, and the second pathway involves a cross-coupling reaction between a bromo-substituted corrole and a suitable substrate to form the four beta-fused aryl rings. These routes are successful to lead to the target tetrabenzocorroles, obtained in both cases as the corresponding Cu complex and with the highest yield obtained via the one-step cross-coupling methodology. Demetalation of the Cu-tetrabenzocorrole produces the corresponding free base; this macrocycle was further exploited to obtain the Sn and Co complexes in good yields.

  DOI：

  10.1021/jo200026u
• 作为产物：
  描述：

  4,5,6,7-四氢异吲哚 、 苯甲醛 在 三氟化硼乙醚 、 2,3-二氯-5,6-二氰基-1,4-苯醌 、 copper diacetate 作用下， 以 二氯甲烷 、 甲醇 为溶剂， 反应 32.0h， 以8%的产率得到(5,10,15-triphenyl-2:3,7:8,12:13,17:18-tetrabutanocorrolato)copper
  参考文献：
  名称：

  Synthetic Routes to 5,10,15-Triaryl-tetrabenzocorroles

  摘要：

  Two different synthetic routes for the preparation of 5,10,15-triaryl-tetrabenzocorroles have been developed. The first approach is based on the condensation of a tetrahydroisoindole with aryl-aldehydes, and the second pathway involves a cross-coupling reaction between a bromo-substituted corrole and a suitable substrate to form the four beta-fused aryl rings. These routes are successful to lead to the target tetrabenzocorroles, obtained in both cases as the corresponding Cu complex and with the highest yield obtained via the one-step cross-coupling methodology. Demetalation of the Cu-tetrabenzocorrole produces the corresponding free base; this macrocycle was further exploited to obtain the Sn and Co complexes in good yields.

  DOI：

  10.1021/jo200026u