N,N'-dimethyl-N,N'-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine | 940301-17-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N,N'-dimethyl-N,N'-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine
• CAS: 940301-17-7
• 化学式: C₂₀H₂₂Cl₂N₂O₄
• 分子量: 425.312
• InChiKey: IRJVTEZDIYLRJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.59
• 重原子数：
  28.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  81.08
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  N,N'-dimethyl-N,N'-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine 、 1,1,3,3-bis[spiro-2',2''-dioxy-1',1''-biphenyl]-5,5-bis(1-methylhydrazido)-1,3,5,2,4,6-cyclotriphosphazene 以 甲醇 、 氯仿 为溶剂， 反应 5.0h， 以78%的产率得到
  参考文献：
  名称：

  Synthesis and spectral characterization of cyclotriphosphazene based 18-membered macrocycles

  摘要：

  New 18-membered cyclotriphosphazene-containing macrocycles 7-10 were obtained by 1 + 1 condensation reaction of [dispiro-N3P3(C12H8O2)(2)((N(Me)N=CH)(2) N4C20H26)] (2) with N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4-methyl-2-formylphenol) (3), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4,5-dimethyl-2-formylphenol) (4), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-chloro-2-formylphenol) (5) and N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-bromo-2-formylphenol) (6), respectively. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.016
• 作为产物：
  描述：

  聚合甲醛 、 5-氯代水杨醛 、 N,N'-二甲基乙二胺 在 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 36.0h， 以82%的产率得到N,N'-dimethyl-N,N'-bis(3-formyl-5-chlorosalicylaldehyde)ethylenediamine
  参考文献：
  名称：

  Synthesis and spectral characterization of cyclotriphosphazene based 18-membered macrocycles

  摘要：

  New 18-membered cyclotriphosphazene-containing macrocycles 7-10 were obtained by 1 + 1 condensation reaction of [dispiro-N3P3(C12H8O2)(2)((N(Me)N=CH)(2) N4C20H26)] (2) with N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4-methyl-2-formylphenol) (3), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(4,5-dimethyl-2-formylphenol) (4), N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-chloro-2-formylphenol) (5) and N,N'-dimethyl-ethylenediamine-1,4-diyldimethylenebis(5-bromo-2-formylphenol) (6), respectively. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.016

文献信息

• A self-assembled pentanuclear single-stranded helicate based on the square-planar coordination geometries
  作者：Huan Liu、Hong Zhou、Zhi-Quan Pan、Dan Hu、Qi-Mao Huang、Han-Ping Zhang、Xue-Lei Hu、Xiang-Gao Meng

  DOI：10.1016/j.inoche.2007.04.002

  日期：2007.7

  two N,N′-dimethyl-N-(3-(2′-aminoethylimine)-5-(chlorosalicylamine))-N′-(3-imine-5-chlorosalicylamine) units are connected by an ethylene, was synthesized and structurally characterized in the solid state as a form of pentanuclear single helicate based on the square-planar coordination geometries.

  摘要 新型双-N4O-六齿席夫碱的铜(II)配合物，其中两个N,N'-二甲基-N-(3-(2'-氨基乙基亚胺)-5-(氯水杨胺))-N' -(3-亚胺-5-氯水杨胺)单元由乙烯连接，在固态下合成并结构表征为基于方形平面配位几何形状的五核单螺旋形式。