3-[3-（9H-咔唑-9-基）苯基]呋喃[2,3-b：5,4-b']二吡啶 | 1443793-91-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 3-[3-（9H-咔唑-9-基）苯基]呋喃[2,3-b：5,4-b']二吡啶
• 英文名称: 3-(3-(carbazole-9-yl)phenyl)pyrido[3',2':4,5]furo[2,3-b]pyridine
• 英文别名: 3-[3-(9H-Carbazol-9-yl)phenyl]furo[2,3-b:5,4-b']dipyridine；4-(3-carbazol-9-ylphenyl)-8-oxa-6,10-diazatricyclo[7.4.0.02,7]trideca-1(9),2(7),3,5,10,12-hexaene
• CAS: 1443793-91-6
• 化学式: C₂₈H₁₇N₃O
• 分子量: 411.462
• InChiKey: XVACVBZZMGRLKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-氨基-5-氯-3-碘吡啶 在 2-双环己基膦-2',6'-二甲氧基联苯 、 potassium phosphate 、 tris-(dibenzylideneacetone)dipalladium(0) 、 四(三苯基膦)钯 、 亚硝酸特丁酯 、 potassium carbonate 、 溶剂黄146 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 73.0h， 生成 3-[3-（9H-咔唑-9-基）苯基]呋喃[2,3-b：5,4-b']二吡啶
  参考文献：
  名称：

  高度缺电子的吡啶并[3'，2'：4,5]呋喃[2,3-b]吡啶是高效绿色磷光有机发光二极管的三重态基质材料的核心结构。

  摘要：

  开发了高度缺电子的吡啶并[3'，2'：4,5]呋喃[2,3-b]吡啶（PFP）作为三重态基质材料和PFP衍生物3-（3-（咔唑-9-基）苯基）吡啶基[3'，2'：4,5]呋喃[2,3-b]吡啶（CzPFP）被合成为双极性主体材料。CzPFP主体材料在单电荷器件中显示出相似的空穴和电子密度，在绿色磷光有机发光二极管中显示出27.7％的高量子效率和86.8 lm W（-1）的高功率效率。

  DOI：

  10.1039/c3cc41605d

文献信息

• POLYCYCLIC AROMATIC COMPOUND, MATERIAL FOR AN ORGANIC DEVICE, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY APPARATUS AND LIGHTING APPARATUS
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US20200207787A1

  公开（公告）日：2020-07-02

  A polycyclic aromatic compound in which a plurality of aromatic rings are connected by a boron atom and an oxygen atom, a sulfur atom or a selenium atom and substituted by a specific aryl such as anthracene, is useful as a material for an organic device. By the polycyclic aromatic compound, an organic EL device having at least one of efficiency and device life can be provided.

  一种多环芳香化合物，其中多个芳香环通过硼原子和氧原子、硫原子或硒原子连接，并以特定的芳基（如蒽）取代，可用作有机器件的材料。通过这种多环芳香化合物，可以提供至少在效率和器件寿命方面具有优势的有机EL器件。
• POLYCYCLIC AROMATIC COMPOUND
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US20200190115A1

  公开（公告）日：2020-06-18

  The present invention provides a novel polycyclic aromatic compound having a plurality of aromatic rings linked by a boron atom, a nitrogen atom, and the like, and thus increases the number of alternatives of a material for an organic electroluminescent (EL) device. Furthermore, the present invention provides an excellent organic EL device by using a novel polycyclic aromatic compound as a material for an organic EL device.

  本发明提供了一种新型多环芳香化合物，其中多个芳香环由硼原子、氮原子等连接，从而增加了有机电致发光（EL）器件材料的选择。此外，本发明通过使用新型多环芳香化合物作为有机EL器件的材料，提供了优秀的有机EL器件。
• 피리도퓨로피리딘 유도체 및 이를 함유하는 유기발광다이오드
  申请人：Industry-Academic Cooperation Foundation, Dankook University 단국대학교 산학협력단(220050166344) BRN ▼106-82-12299

  公开号：KR101627026B1

  公开（公告）日：2016-06-07

  피리도퓨로피리딘 유도체 및 이를 구비하는 유기발광다이오드를 제공한다. 피리도퓨로피리딘 유도체는 전자이동도 뿐 아니라 정공이동도가 우수하고, 삼중항 에너지가 비교적 높아 유기발광다이오드에 사용하는 경우, 유기발광다이오드의 효율 향상 및 구동 전압 감소를 기대할 수 있다.

  提供吡啶二嗪衍生物及其所配备的有机发光二极管。吡啶二嗪衍生物不仅具有电子迁移率，而且具有优异的空穴迁移率，三重态能量相对较高，因此在用于有机发光二极管时，可以期望提高有机发光二极管的效率并降低驱动电压。
• Polycyclic aromatic compound, material for an organic device, organic electroluminescent element, display apparatus and lighting apparatus
  申请人：Kwansei Gakuin Educational Foundation

  公开号：US11248009B2

  公开（公告）日：2022-02-15

  A polycyclic aromatic compound in which a plurality of aromatic rings are connected by a boron atom and an oxygen atom, a sulfur atom or a selenium atom and substituted by a specific aryl such as anthracene, is useful as a material for an organic device. By the polycyclic aromatic compound, an organic EL device having at least one of efficiency and device life can be provided.

  一种多环芳香族化合物，其中多个芳香环通过硼原子和氧原子、硫原子或硒原子连接，并被特定芳基（如蒽）取代，可用作有机器件的材料。通过这种多环芳香族化合物，可以提供一种有机 EL 器件，该器件具有效率和器件寿命中的至少一个优点。
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20210098713A1

  公开（公告）日：2021-04-01

  An organic electroluminescence device of the present embodiments includes a first electrode, a second electrode on the first electrode, and a first emission layer and a second emission layer, both between the first electrode and the second electrode, wherein the first emission layer includes a first host and a first dopant including an anthracene-based compound, the second emission layer includes a second host represented by Formula H-1 and a second dopant including an organometal compound, and the first emission layer and the second emission layer are adjacent to each other. The device of the present embodiments thereby shows high emission efficiency and long-life characteristics.