| 1427763-42-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1427763-42-5
• 化学式: C₂₂H₂₆CuN₅O₃*ClO₄
• 分子量: 571.477
• InChiKey: MPFZDKKNGRWKAK-WACBHLOPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetraaza Schiff base macrocyclic ligand 、 copper nitrate trihydrate 在 sodium perchlorate 作用下， 以 乙醇 为溶剂， 反应 6.0h， 以55%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterization of a new Schiff base macrocyclic ligand containing a piperazine head unit and its metal complexes. Crystal structure of the Co(II) complex

  摘要：

  A new macrocyclic Schiff base ligand, L, was synthesized by the condensation reaction of 1,4-bis(2-formylphenyl)piperazine and 1,4-diaminobutane in acetonitrile. The Schiff base ligand was characterized by elemental analysis, IR and mass spectroscopy. Three new Co(II), Cu(II) and Zn(II) complexes, [COL(NO3)]-ClO4, [CuL(NO3)]ClO4 and [ZnL(NO3)]ClO4, were prepared and characterized by elemental analysis, IR, FAB-MS, conductivity measurements and in the case of [ZnL(NO3)]ClO4 by H-1 NMR spectroscopy. The X-ray crystal structure of [CoL(NO3)]ClO4 showed that the complex contains Co(II) in a distorted octahedral geometry with an N4O2 core. Also, theoretical studies on the interaction of the nitrate ion and metal ions were carried out. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.12.020