C60(CH2SiMe2C6H13)H | 1082487-38-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: C60(CH2SiMe2C6H13)H
• 英文别名: 1-(Hexyldimethylsilylmethyl)-1,9-dihydro(C60-I_h)[5,6]fullerene
• CAS: 1082487-38-4
• 化学式: C₆₉H₂₂Si
• 分子量: 879.019
• InChiKey: CVOVGWWYRCXEDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.43
• 重原子数：
  70.0
• 可旋转键数：
  7.0
• 环数：
  32.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  C60(CH2SiMe2C6H13)H 在 potassium tert-butylate 、 碘 作用下， 以 四氢呋喃 、 邻二氯苯 为溶剂， 反应 0.27h， 生成
  参考文献：
  名称：

  Regioselective [2 + 2] Cycloaddition of a Fullerene Dimer with an Alkyne Triggered by Thermolysis of an Interfullerene C–C Bond

  摘要：

  Heating of a singly bonded fullerene dimer in the presence of an alkyne forms a cyclobutene structure on only one of the two fullerene moieties, through a stereo- and regioselective [2 + 2] cycloaddition. Experimental and theoretical data suggest that the reaction is triggered by cleavage of the interfullerene C-C bond and formation of a monomeric fullerene radical.

  DOI：

  10.1021/ol400713t
• 作为产物：
  描述：

  (C6H13)Me2SiCH2MgCl 、 足球烯 在 N,N-二甲基甲酰胺 作用下， 以 四氢呋喃 、 邻二氯苯 为溶剂， 反应 0.08h， 以83%的产率得到C60(CH2SiMe2C6H13)H
  参考文献：
  名称：

  Regioselective Synthesis of 1,4-Di(organo)[60]fullerenes through DMF-assisted Monoaddition of Silylmethyl Grignard Reagents and Subsequent Alkylation Reaction

  摘要：

  Monoaddition of Grignard reagents, in particular tri(organo)silylmethyl magnesium chlorides, to [60]fullerene took place smoothly in the presence of dimethylformamideto produce (organo)(hydro)[60]fullerenes, (C60RH)-H-1, in good yield (up to 93% isolated yield). The hydrofullerene was then deprotonated to generate the corresponding anion, C60R-, which was then alkylated to obtain 58 pi-electron di(organo)[60]fullerenes, (C60RR2)-R-1, in good to high yield (up to 93% overall yield). The two-step methodology provides a wide variety of 1,4-di(organo)[60] fullerenes bearing the same or different organic addends on the [60] fullerene core. By changing the addends, one can control the chemical and physical properties of the compounds at the molecular and bulk levels.

  DOI：

  10.1021/ja8041299