| 1159267-23-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• CAS: 1159267-23-8
• 化学式: C₅H₁₂Cl₆Ge₂Si
• 分子量: 458.134
• InChiKey: XGXJXYAHFNPPKJ-UHFFFAOYSA-N

物化性质

• 沸点：
  312.4±52.0 °C(predicted)

反应信息

• 作为产物：
  描述：

  trichlorogermane etherate 、 乙烯基三甲基硅烷 以 neat (no solvent) 为溶剂， 以4.3%的产率得到
  参考文献：
  名称：

  Hydrogermylation of silyl-substituted ethylenes with trimethylgermane and trichlorogermane etherate

  摘要：

  Investigation of the reaction of some vinylsilanes of the general formula Cl3-n(CH3)(n)SiCH=CH2 (n = 0,1,2,3) and 1,2-bis(trimethylsilyl)ethylene with trimethylgermane and trichlorogermane etherate was carried out. It was established that hydrogermylation only at the use of HGeCl3 center dot 2Et(2)O was sensitive to the nature of the substituting silyl groups in vinylsilanes. Nucleophilic mechanism of the reaction of trichlorogermane etherate with vinylsilanes is suggested.

  DOI：

  10.1134/s1070363208050101