Pd(bis-2,9-dimesityl-phenanthroline)(NO₃)₂ | 1417373-26-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Pd(bis-2,9-dimesityl-phenanthroline)(NO₃)₂
• CAS: 1417373-26-2
• 化学式: C₃₀H₂₈N₄O₆Pd
• 分子量: 646.996
• InChiKey: VMRISANFEOVXTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,4,6-三(4-吡啶)1,3,5-三嗪 、 Pd(bis-2,9-dimesityl-phenanthroline)(NO₃)₂ 以 水 、 乙腈 为溶剂， 反应 1.0h， 以100%的产率得到
  参考文献：
  名称：

  Noncovalent Tailoring of the Binding Pocket of Self-Assembled Cages by Remote Bulky Ancillary Groups

  摘要：

  The binding properties of a self-assembled coordination cage were subtly tuned by ancillary groups on the metal corners of the cage. Since the bulky mesityl groups of the ligand hang over the cage cavity, the effective cavity volume is reduced. Due to the tighter guest packing inside the shrunken cavity, smaller guests were efficiently bound and guest motion was restricted even at high temperatures.

  DOI：

  10.1021/ja311373f
• 作为产物：
  描述：

  2,9-dimesityl-1,10-phenanthroline 以 乙腈 为溶剂， 反应 4.0h， 生成 Pd(bis-2,9-dimesityl-phenanthroline)(NO₃)₂
  参考文献：
  名称：

  Noncovalent Tailoring of the Binding Pocket of Self-Assembled Cages by Remote Bulky Ancillary Groups

  摘要：

  The binding properties of a self-assembled coordination cage were subtly tuned by ancillary groups on the metal corners of the cage. Since the bulky mesityl groups of the ligand hang over the cage cavity, the effective cavity volume is reduced. Due to the tighter guest packing inside the shrunken cavity, smaller guests were efficiently bound and guest motion was restricted even at high temperatures.

  DOI：

  10.1021/ja311373f