| 38412-91-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 38412-91-8
• 化学式: C₃H₆O*Cl₃Cu
• 分子量: 227.985
• InChiKey: NFQCYIBLIYVRHT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.66
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  copper(II) nitrate 、 丙酮 、 lithium chloride 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Ionization Differences Between Coordination States of a Cation. Octahedral—Tetrahedral Equilibrium of Transition‐Element Chlorides in Dimethylformamide

  摘要：

  In a high-dielectric-constant, low-base-strength medium, such as dimethyl formamide, formation of chloride complexes of the first transition elements in the tetrahedral configuration is promoted. The effect is linked with a greater dissociation (weaker anion complexing) of the octahedral configuration, as indicated by the over-all equilibrium expression 2oct(MCl2X4)= oct(MClX5+)· tet(MCl3X)−+2X.The corresponding change in the absorption spectrum has been followed for the chlorides of Mn(II), Fe(II), Fe(III), Co(II), Ni(II), and Cu(II). The spectra with and without added LiCl are described. Some relations to current ligand-field theories concerning the configuration change are pointed out.

  DOI：

  10.1063/1.1732422

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B3, 197, page 1427 - 1430
  作者：

  DOI：——

  日期：——